Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

Graeme Cooke; F. M A Duclairoir; Arno Kraft; Georgina Rosair; Vincent M. Rotello

doi:10.1016/j.tetlet.2003.10.218

Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

Graeme Cooke, F. M A Duclairoir, Arno Kraft, Georgina Rosair, Vincent M. Rotello

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol ^-1 stabilisation of the ferrocenium state. © 2003 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	557-560
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	3
DOIs	https://doi.org/10.1016/j.tetlet.2003.10.218
Publication status	Published - 12 Jan 2004

Keywords

Amidine
Electrochemistry
Ferrocenecarboxylic acid
Recognition

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10.1016/j.tetlet.2003.10.218

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abstract = "Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol -1 stabilisation of the ferrocenium state. {\textcopyright} 2003 Elsevier Ltd. All rights reserved.",

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AU - Cooke, Graeme

AU - Duclairoir, F. M A

AU - Kraft, Arno

AU - Rosair, Georgina

AU - Rotello, Vincent M.

PY - 2004/1/12

Y1 - 2004/1/12

N2 - Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol -1 stabilisation of the ferrocenium state. © 2003 Elsevier Ltd. All rights reserved.

AB - Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol -1 stabilisation of the ferrocenium state. © 2003 Elsevier Ltd. All rights reserved.

KW - Amidine

KW - Electrochemistry

KW - Ferrocenecarboxylic acid

KW - Recognition

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U2 - 10.1016/j.tetlet.2003.10.218

DO - 10.1016/j.tetlet.2003.10.218

M3 - Article

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 3

ER -

Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

Abstract

Keywords

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