Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

Graeme Cooke; F. M A Duclairoir; Arno Kraft; Georgina Rosair; Vincent M. Rotello

doi:10.1016/j.tetlet.2003.10.218

Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

Graeme Cooke, F. M A Duclairoir, Arno Kraft, Georgina Rosair, Vincent M. Rotello

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol ^-1 stabilisation of the ferrocenium state. © 2003 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	557-560
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	3
DOIs	https://doi.org/10.1016/j.tetlet.2003.10.218
Publication status	Published - 12 Jan 2004

Keywords

Amidine
Electrochemistry
Ferrocenecarboxylic acid
Recognition

Access to Document

10.1016/j.tetlet.2003.10.218

Cite this

@article{f1d9eb667be54a44a7fb3ee50d1b5054,

title = "Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine",

abstract = "Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol -1 stabilisation of the ferrocenium state. {\textcopyright} 2003 Elsevier Ltd. All rights reserved.",

keywords = "Amidine, Electrochemistry, Ferrocenecarboxylic acid, Recognition",

author = "Graeme Cooke and Duclairoir, {F. M A} and Arno Kraft and Georgina Rosair and Rotello, {Vincent M.}",

year = "2004",

month = jan,

day = "12",

doi = "10.1016/j.tetlet.2003.10.218",

language = "English",

volume = "45",

pages = "557--560",

journal = "Tetrahedron Letters",

publisher = "Elsevier Ltd",

number = "3",

}

TY - JOUR

T1 - Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

AU - Cooke, Graeme

AU - Duclairoir, F. M A

AU - Kraft, Arno

AU - Rosair, Georgina

AU - Rotello, Vincent M.

PY - 2004/1/12

Y1 - 2004/1/12

N2 - Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol -1 stabilisation of the ferrocenium state. © 2003 Elsevier Ltd. All rights reserved.

AB - Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N'-diethylsubstituted benzamidine leads to a -0.27V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26kJmol -1 stabilisation of the ferrocenium state. © 2003 Elsevier Ltd. All rights reserved.

KW - Amidine

KW - Electrochemistry

KW - Ferrocenecarboxylic acid

KW - Recognition

UR - http://www.scopus.com/inward/record.url?scp=0346363693&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2003.10.218

DO - 10.1016/j.tetlet.2003.10.218

M3 - Article

VL - 45

SP - 557

EP - 560

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 3

ER -

Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this