Preparation, structure, and properties of paramagnetic, heterobinuclear complexes containing nickel and molybdenum or tungsten. X-ray crystal structure of [NIW(CO)3(PPh3)2(η-C5H 5)]

Laurence Carlton, W. Edward Lindsell, Kevin J. McCullough, Peter N. Preston

Research output: Contribution to journalArticle

Abstract

New paramagnetic complexes [MNi(CO)3-(PPh3)2(?-C5H 5)] (M = Mo, W) have been characterized and studied by ESR spectroscopy, EHMO calculations, and cyclic voltammetry; the structure of crystalline [NiW-(CO)3(PPh3)2(?-C5H 5)] has been determined by X-ray diffraction. © 1985 American Chemical Society.

Original languageEnglish
Pages (from-to)1138-1140
Number of pages3
JournalOrganometallics
Volume4
Issue number6
DOIs
Publication statusPublished - 1985

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Tungsten
Molybdenum
Carbon Monoxide
Nickel
Crystal structure
X rays
Cyclic voltammetry
Paramagnetic resonance
Spectroscopy
Crystalline materials
X ray diffraction

Cite this

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title = "Preparation, structure, and properties of paramagnetic, heterobinuclear complexes containing nickel and molybdenum or tungsten. X-ray crystal structure of [NIW(CO)3(PPh3)2(η-C5H 5)]",
abstract = "New paramagnetic complexes [MNi(CO)3-(PPh3)2(?-C5H 5)] (M = Mo, W) have been characterized and studied by ESR spectroscopy, EHMO calculations, and cyclic voltammetry; the structure of crystalline [NiW-(CO)3(PPh3)2(?-C5H 5)] has been determined by X-ray diffraction. {\circledC} 1985 American Chemical Society.",
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Preparation, structure, and properties of paramagnetic, heterobinuclear complexes containing nickel and molybdenum or tungsten. X-ray crystal structure of [NIW(CO)3(PPh3)2(η-C5H 5)]. / Carlton, Laurence; Lindsell, W. Edward; McCullough, Kevin J.; Preston, Peter N.

In: Organometallics, Vol. 4, No. 6, 1985, p. 1138-1140.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Preparation, structure, and properties of paramagnetic, heterobinuclear complexes containing nickel and molybdenum or tungsten. X-ray crystal structure of [NIW(CO)3(PPh3)2(η-C5H 5)]

AU - Carlton, Laurence

AU - Lindsell, W. Edward

AU - McCullough, Kevin J.

AU - Preston, Peter N.

PY - 1985

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