Preparation, structure, and properties of paramagnetic, heterobinuclear complexes containing nickel and molybdenum or tungsten. X-ray crystal structure of [NIW(CO)3(PPh3)2(η-C5H 5)]

Laurence Carlton, W. Edward Lindsell, Kevin J. McCullough, Peter N. Preston

Research output: Contribution to journalArticle

Abstract

New paramagnetic complexes [MNi(CO)3-(PPh3)2(?-C5H 5)] (M = Mo, W) have been characterized and studied by ESR spectroscopy, EHMO calculations, and cyclic voltammetry; the structure of crystalline [NiW-(CO)3(PPh3)2(?-C5H 5)] has been determined by X-ray diffraction. © 1985 American Chemical Society.

Original languageEnglish
Pages (from-to)1138-1140
Number of pages3
JournalOrganometallics
Volume4
Issue number6
DOIs
Publication statusPublished - 1985

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