Preparation of cis-bis-acetylene-bis(pentafluorophenyl)-palladium(II) and -platinum(II) complexes, crystal structure of cis-[Pt(C6F5)2 (PhC≡CPh)2]

Rafael Usón; Juan Forniés; Milagros Tomás; Babil Menjón; Alan J. Welch

doi:10.1016/0022-328X(86)80160-7

Preparation of cis-bis-acetylene-bis(pentafluorophenyl)-palladium(II) and -platinum(II) complexes, crystal structure of cis-[Pt(C₆F₅)₂ (PhC≡CPh)₂]

Rafael Usón^*, Juan Forniés, Milagros Tomás, Babil Menjón, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Treatment of cis-[M(C₆F₅)₂(THF)₂] (M = Pd, Pt; THF = tetrahydrofuran) with PhC≡CPh has given the novel bis-acetylene-palladium(II) and -platinum(II) complexes cis-[M(C₆F₅)₂(PhC≡CPh)₂]; these are stable even though there seems to be no significant π-back bonding according to the X-ray structure of the platinum complex.

Original language	English
Pages (from-to)	C24-C26
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	304
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(86)80160-7
Publication status	Published - 6 May 1986

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Preparation of cis-bis-acetylene-bis(pentafluorophenyl)-palladium(II) and -platinum(II) complexes, crystal structure of cis-[Pt(C6F5)2 (PhC≡CPh)2]",

abstract = "Treatment of cis-[M(C6F5)2(THF)2] (M = Pd, Pt; THF = tetrahydrofuran) with PhC≡CPh has given the novel bis-acetylene-palladium(II) and -platinum(II) complexes cis-[M(C6F5)2(PhC≡CPh)2]; these are stable even though there seems to be no significant π-back bonding according to the X-ray structure of the platinum complex.",

author = "Rafael Us{\'o}n and Juan Forni{\'e}s and Milagros Tom{\'a}s and Babil Menj{\'o}n and Welch, \{Alan J.\}",

year = "1986",

month = may,

day = "6",

doi = "10.1016/0022-328X(86)80160-7",

language = "English",

volume = "304",

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journal = "Journal of Organometallic Chemistry",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Preparation of cis-bis-acetylene-bis(pentafluorophenyl)-palladium(II) and -platinum(II) complexes, crystal structure of cis-[Pt(C6F5)2 (PhC≡CPh)2]

AU - Usón, Rafael

AU - Forniés, Juan

AU - Tomás, Milagros

AU - Menjón, Babil

AU - Welch, Alan J.

PY - 1986/5/6

Y1 - 1986/5/6

N2 - Treatment of cis-[M(C6F5)2(THF)2] (M = Pd, Pt; THF = tetrahydrofuran) with PhC≡CPh has given the novel bis-acetylene-palladium(II) and -platinum(II) complexes cis-[M(C6F5)2(PhC≡CPh)2]; these are stable even though there seems to be no significant π-back bonding according to the X-ray structure of the platinum complex.

AB - Treatment of cis-[M(C6F5)2(THF)2] (M = Pd, Pt; THF = tetrahydrofuran) with PhC≡CPh has given the novel bis-acetylene-palladium(II) and -platinum(II) complexes cis-[M(C6F5)2(PhC≡CPh)2]; these are stable even though there seems to be no significant π-back bonding according to the X-ray structure of the platinum complex.

UR - https://www.scopus.com/pages/publications/3743072847

U2 - 10.1016/0022-328X(86)80160-7

DO - 10.1016/0022-328X(86)80160-7

M3 - Article

AN - SCOPUS:3743072847

SN - 0022-328X

VL - 304

SP - C24-C26

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Preparation of cis-bis-acetylene-bis(pentafluorophenyl)-palladium(II) and -platinum(II) complexes, crystal structure of cis-[Pt(C₆F₅)₂ (PhC≡CPh)₂]

Abstract

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