Preparation of cis-bis-acetylene-bis(pentafluorophenyl)-palladium(II) and -platinum(II) complexes, crystal structure of cis-[Pt(C6F5)2 (PhC≡CPh)2]

Rafael Usón, Juan Forniés, Milagros Tomás, Babil Menjón, Alan J. Welch

Research output: Contribution to journalArticle

Abstract

Treatment of cis-[M(C6F5)2(THF)2] (M = Pd, Pt; THF = tetrahydrofuran) with PhC≡CPh has given the novel bis-acetylene-palladium(II) and -platinum(II) complexes cis-[M(C6F5)2(PhC≡CPh)2]; these are stable even though there seems to be no significant π-back bonding according to the X-ray structure of the platinum complex.

Original languageEnglish
Pages (from-to)C24-C26
Number of pages3
JournalJournal of Organometallic Chemistry
Volume304
Issue number3
DOIs
Publication statusPublished - 6 May 1986

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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