Preparation and characterization of (monomethyl itaconate)-(methyl methacrylate) and of (itaconic anhydride)-(methyl methacrylate) copolymers

A. F. Miles, J. M G Cowie

Research output: Contribution to journalArticle

Abstract

The free radical copolymerizations and thermal characterization of monomethyl itaconate (MMI)-methyl methacrylate (MMA) and of itaconic anhydride (IT.ANH)-MMA have been investigated in order to prepare samples suitable for assessment as thermally crosslinkable electron beam resist materials. For the copolymerization of MMI and MMA in solution in benzene at 70°, monomer reactivity ratios rMMI = 0.16 ± 0.09 and rMMA = 1.08 ± 0.5 were found using a non-linear least squares curve fitting technique. For the copolymerization of IT.ANH with MMA in bulk at 70°, rIT.ANH = 0.99 ± 0.40 and rMMA = 0.18 ± 0.7. The glass transition temperatures and thermal stabilities of each series of copolymers have been investigated using differential scanning calorimetry and thermogravimetric analysis techniques in order to determine suitable conditions for resist processing. © 1991.

Original languageEnglish
Pages (from-to)165-170
Number of pages6
JournalEuropean Polymer Journal
Volume27
Issue number2
Publication statusPublished - 1991

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Methacrylates
Anhydrides
Copolymers
Copolymerization
Curve fitting
Benzene
Free Radicals
Thermogravimetric analysis
Differential scanning calorimetry
Electron beams
Thermodynamic stability
Monomers
itaconic acid
Processing

Cite this

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abstract = "The free radical copolymerizations and thermal characterization of monomethyl itaconate (MMI)-methyl methacrylate (MMA) and of itaconic anhydride (IT.ANH)-MMA have been investigated in order to prepare samples suitable for assessment as thermally crosslinkable electron beam resist materials. For the copolymerization of MMI and MMA in solution in benzene at 70°, monomer reactivity ratios rMMI = 0.16 ± 0.09 and rMMA = 1.08 ± 0.5 were found using a non-linear least squares curve fitting technique. For the copolymerization of IT.ANH with MMA in bulk at 70°, rIT.ANH = 0.99 ± 0.40 and rMMA = 0.18 ± 0.7. The glass transition temperatures and thermal stabilities of each series of copolymers have been investigated using differential scanning calorimetry and thermogravimetric analysis techniques in order to determine suitable conditions for resist processing. {\circledC} 1991.",
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Preparation and characterization of (monomethyl itaconate)-(methyl methacrylate) and of (itaconic anhydride)-(methyl methacrylate) copolymers. / Miles, A. F.; Cowie, J. M G.

In: European Polymer Journal, Vol. 27, No. 2, 1991, p. 165-170.

Research output: Contribution to journalArticle

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