TY - JOUR
T1 - Preparation and characterisation of some nickel(II) tetra-aza macrocyclic complexes bearing pendant polymerisable groups as part of the ligand superstructure
AU - Cameron, James H.
AU - Graham, Stephen
PY - 1989
Y1 - 1989
N2 - The synthesis and characterisation of some new nickel(II) macrocyclic complexes of the 'lacunar' type have been performed where the ligand has, as part of the ligand superstructure, either 4-vinylphenyl or allyl groups capable of undergoing polymerisation reactions with selected comonomers. The n.m.r. spectra of a number of these new complexes show them to be fluxional on the n.m.r. time-scale and the nature of this fluxional behaviour is discussed. Some copolymerisation reactions of these complexes, with styrene or methyl methacrylate comonomers, have been performed.
AB - The synthesis and characterisation of some new nickel(II) macrocyclic complexes of the 'lacunar' type have been performed where the ligand has, as part of the ligand superstructure, either 4-vinylphenyl or allyl groups capable of undergoing polymerisation reactions with selected comonomers. The n.m.r. spectra of a number of these new complexes show them to be fluxional on the n.m.r. time-scale and the nature of this fluxional behaviour is discussed. Some copolymerisation reactions of these complexes, with styrene or methyl methacrylate comonomers, have been performed.
UR - http://www.scopus.com/inward/record.url?scp=37049071407&partnerID=8YFLogxK
U2 - 10.1039/DT9890001599
DO - 10.1039/DT9890001599
M3 - Article
SN - 1472-7773
SP - 1599
EP - 1608
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 8
ER -