Precipitating amino acid solutions

L. V. van der Ham, E. L. V. Goetheer, Eva Sanchez Fernandez, M. R. M. Abu-Zahra, T. J. H. Vlugt

Research output: Chapter in Book/Report/Conference proceedingChapter

2 Citations (Scopus)

Abstract

Aqueous amino acid salt solutions that precipitate due to CO2 absorption are a relatively novel and promising class of solvents. Although the presence of solids in the process stream requires adequate measures related to slurry handling and crystallization control, precipitation also increases the solvent CO2 capacity and the energy performance of the stripper. By using an additional solidliquid separation step to concentrate the slurry before it is sent to the stripper, known as the DECAB+ process, the energy performance can be further improved. Most of the current experimental work on these systems focuses on the amino acids taurine, α- and β-alanine, sarcosine, glycine, and proline, neutralized with equimolar amounts of potassium hydroxide. Investigated properties include the CO2 concentration at which precipitation is first observed, which is closely related to the solubility of the amino acid, the composition of the precipitate, and the CO2 absorption rate. The precipitate typically contains pure amino acids and/or bicarbonate, depending on the amino acid solubility. Shortcut process simulations have been used to estimate the energy performance of absorption processes using precipitating amino acids, so far focusing on 4M KOH + taurine (K-tau) and 4M KOH +α-alanine (K-α-ala) solutions. Specific regeneration duties below 2GJ/ton CO2 seem possible for the DECAB+ process when using K-α-ala and lean vapor compressor (LVC). Compared to a conventional process using 30wt % monoethanolamine and LVC, this corresponds to a reduction of 35% in the regeneration duty. Future research should focus on more-detailed process simulations, based on a predictive thermodynamic model that consistently describes the vaporliquidsolid equilibria of the system. Demonstration of the DECAB+ process on a pilot scale is also highly recommended, with a special focus on the crystallization and slurry handling process steps and units.

Original languageEnglish
Title of host publicationAbsorption-Based Post-Combustion Capture of Carbon Dioxide
PublisherElsevier
Pages104-119
Number of pages16
ISBN (Electronic)9780081005156
ISBN (Print)9780081005149
DOIs
Publication statusPublished - 2016

Keywords

  • Amino acids
  • Experimental investigation
  • Precipitation
  • Process simulation
  • Roadmap

ASJC Scopus subject areas

  • Medicine (miscellaneous)

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  • Cite this

    van der Ham, L. V., Goetheer, E. L. V., Sanchez Fernandez, E., Abu-Zahra, M. R. M., & Vlugt, T. J. H. (2016). Precipitating amino acid solutions. In Absorption-Based Post-Combustion Capture of Carbon Dioxide (pp. 104-119). Elsevier. https://doi.org/10.1016/B978-0-08-100514-9.00005-6