Phthalocyanine pigments: General principles

Robert Christie*, Adrian Abel

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

This chapter describes some of the fundamental chemical and structural principles underlying the phthalocyanine system. Historically, phthalocyanines had been isolated as insoluble blue products in the early twentieth century, although the structures were not established at the time. After the serendipitous re-discovery of metal complex phthalocyanines by industry, and the elucidation of their structures, copper phthalocyanine (CuPc) pigments were introduced industrially in the 1930s to become, and remain, by far the most important blue and green organic pigments, finding almost universal use as colorants for paints, printing inks, plastics, and a wide range of other applications. The phthalocyanines have become one of the most extensively studied classes of organic compounds, because of their unique molecular structures, light absorption properties that produce strong, bright colors, and their exceptionally high stability. While their dominant use is as colorants, they are also of interest for a range of other applications, for example in electronic devices, biological applications, and as catalysts.

Original languageEnglish
Pages (from-to)671-677
Number of pages7
JournalPhysical Sciences Reviews
Volume6
Issue number11
Early online date29 Jun 2021
DOIs
Publication statusPublished - 1 Nov 2021

Keywords

  • 16-membered ring
  • chlorophyll
  • copper phthalocyanine
  • iron phthalocyanine
  • metal-free phthalocyanine
  • phthalic anhydride
  • phthalimide
  • phthalocyanine pigments
  • phthalonitrile
  • resonance-stabilization
  • Scottish Dyes
  • π-functional materials

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Physics and Astronomy(all)

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