Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions

Marjan Hosseinzadeh, Sergio Sanz, Jan van Leusen, Natalya V. Izarova, Euan K. Brechin, Scott J. Dalgarno, Paul Kögerler

Research output: Contribution to journalArticlepeer-review

Abstract

Combination of phosphoryl and calix[4]arene moieties in the same organic framework (LPO) directs the formation of homoleptic double-decker complexes [LnIII(LPO)2](OTf)3 for Ln = Tb and Dy, with the latter displaying slow relaxation of the magnetisation.

Original languageEnglish
Pages (from-to)8087-8090
Number of pages4
JournalChemical Communications
Volume57
Issue number65
Early online date20 Jul 2021
DOIs
Publication statusPublished - 21 Aug 2021

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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