Phonon-Glass and Heterogeneous Electrical Transport in A-Site Deficient SrTiO3

Srinivasa R. Popuri, Rodolphe Decourt, Jason A. McNulty, Michael Pollet, Andrew Dominic Fortes, Finlay D. Morrison, Mark S. Senn, Jan-Willem Gezienes Bos

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Abstract

The phonon-glass electron crystal concept is one of the key guiding principles for the development of efficient thermoelectric materials. Here, we confirm that SrTiO 3 becomes a phonon-glass for large numbers of A-site vacancies in the Sr 1-x La 0.67x0.33x TiO 3 series and show that its electron crystal properties are stymied by the presence of a core-shell grain structure. Thermal conductivity, heat capacity, and neutron powder diffraction, complemented by representational analysis and phonon calculations, were used to investigate the thermal transport. This reveals that the heat carrying modes are dominated by Sr motions and that these become more localized upon the introduction of the A-site vacancies, consistent with the observed phonon-glass state. Impedance spectroscopy and direct current electrical measurements were used to probe the electrical properties of insulating and conducting samples. This reveals the coring of grains due to oxidation on cooling from sintering temperatures. The resultant insulating shell limits the thermoelectric power factor to S 2 /ρ = 0.45 mW m -1 K -2 and the figure-of merit to ZT = 0.15 at 900 K for Sr 0.20 La 0.530.27 Ti 0.95 Nb 0.05 O 3?δ . The thermal properties of these materials are, therefore, controlled by an intrinsic feature of the microstructure (i.e., the A-site vacancies), whereas the electrical properties are grain boundary limited, which in principle can be controlled independently to raise S 2 /ρ and ZT.

Original languageEnglish
Pages (from-to)5198–5208
Number of pages11
JournalJournal of Physical Chemistry C
Volume123
Issue number9
Early online date4 Feb 2019
DOIs
Publication statusPublished - 7 Mar 2019

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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    Popuri, S. R., Decourt, R., McNulty, J. A., Pollet, M., Fortes, A. D., Morrison, F. D., Senn, M. S., & Bos, J-W. G. (2019). Phonon-Glass and Heterogeneous Electrical Transport in A-Site Deficient SrTiO3. Journal of Physical Chemistry C, 123(9), 5198–5208. https://doi.org/10.1021/acs.jpcc.8b10520