Phase coexistence in polydisperse charged hard-sphere fluids: Mean spherical approximation

Yurij V. Kalyuzhnyi; Gerhard Kahl; Peter T. Cummings

doi:10.1063/1.1737291

Phase coexistence in polydisperse charged hard-sphere fluids: Mean spherical approximation

Yurij V. Kalyuzhnyi^*, Gerhard Kahl, Peter T. Cummings

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The phase behavior of a polydisperse fluid mixtures of charged hard-sphere (CHS) was investigated. The distribution functions of the coexisting daughter phases and their charge distributions were also discussed. The full phase diagram in terms of cloud and shadow curves were calculated. It was shown that the polydisperse fluid mixture of CHS belongs to the class of truncatable free energy models.

Original language	English
Pages (from-to)	10133-10145
Number of pages	13
Journal	Journal of Chemical Physics
Volume	120
Issue number	21
DOIs	https://doi.org/10.1063/1.1737291
Publication status	Published - 1 Jun 2004

Keywords

Phase transitions
Energy model
Thermodynamic properties
Electrolytes
Statistical mechanics models

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1737291

Cite this

@article{63cd0c771ebf4ea4a6e408e6ab060f1d,

title = "Phase coexistence in polydisperse charged hard-sphere fluids: Mean spherical approximation",

abstract = "The phase behavior of a polydisperse fluid mixtures of charged hard-sphere (CHS) was investigated. The distribution functions of the coexisting daughter phases and their charge distributions were also discussed. The full phase diagram in terms of cloud and shadow curves were calculated. It was shown that the polydisperse fluid mixture of CHS belongs to the class of truncatable free energy models.",

keywords = "Phase transitions, Energy model, Thermodynamic properties, Electrolytes, Statistical mechanics models",

author = "Kalyuzhnyi, \{Yurij V.\} and Gerhard Kahl and Cummings, \{Peter T.\}",

year = "2004",

month = jun,

day = "1",

doi = "10.1063/1.1737291",

language = "English",

volume = "120",

pages = "10133--10145",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "21",

}

TY - JOUR

T1 - Phase coexistence in polydisperse charged hard-sphere fluids: Mean spherical approximation

AU - Kalyuzhnyi, Yurij V.

AU - Kahl, Gerhard

AU - Cummings, Peter T.

PY - 2004/6/1

Y1 - 2004/6/1

N2 - The phase behavior of a polydisperse fluid mixtures of charged hard-sphere (CHS) was investigated. The distribution functions of the coexisting daughter phases and their charge distributions were also discussed. The full phase diagram in terms of cloud and shadow curves were calculated. It was shown that the polydisperse fluid mixture of CHS belongs to the class of truncatable free energy models.

AB - The phase behavior of a polydisperse fluid mixtures of charged hard-sphere (CHS) was investigated. The distribution functions of the coexisting daughter phases and their charge distributions were also discussed. The full phase diagram in terms of cloud and shadow curves were calculated. It was shown that the polydisperse fluid mixture of CHS belongs to the class of truncatable free energy models.

KW - Phase transitions

KW - Energy model

KW - Thermodynamic properties

KW - Electrolytes

KW - Statistical mechanics models

UR - https://www.scopus.com/pages/publications/2942653223

U2 - 10.1063/1.1737291

DO - 10.1063/1.1737291

M3 - Article

AN - SCOPUS:2942653223

SN - 0021-9606

VL - 120

SP - 10133

EP - 10145

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 21

ER -

Phase coexistence in polydisperse charged hard-sphere fluids: Mean spherical approximation

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this