Peripheral functionalisation of the nickel(II) complex of a tetradentate (N3O) ligand via a pendant amine substituent

James H. Cameron, Heather B. Harvey, John J. Liggat, Ian Soutar

Research output: Contribution to journalArticle

Abstract

The reactivity of the nickel(II) complex (1) of a tetradentate (N3O) ligand containing a pendant amine group has been demonstrated by reaction with a variety of electrophilic reagents, including iodomethane, acetyl chloride, benzoyl chloride, 4-vinylbenzoyl chloride, acryloyl chloride, toluene-p-sulphonyl chloride, N-acryloylsuccinimide, and the copolymer of N-acryloylsuccinimide and n-butyl acrylate, yielding a series of new complexes. The complex containing a p-vinylbenzoyl substituent group behaved as a comonomer in free-radical-initiated copolymerisation with methyl methacrylate to produce a polymer containing a covalently bound complex. A new fifteen-membered asymmetric macrocyclic complex has been prepared by the self-condensation reaction of complex (1).

Original languageEnglish
Pages (from-to)2029-2034
Number of pages6
JournalJournal of the Chemical Society, Dalton Transactions
Issue number7
DOIs
Publication statusPublished - 1990

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Condensation reactions
Methacrylates
Toluene
Nickel
Copolymerization
Free Radicals
Amines
Chlorides
Polymers
Copolymers
Ligands
acryloyl chloride
acetyl chloride
benzoyl chloride
methyl iodide
n-butyl acrylate

Cite this

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title = "Peripheral functionalisation of the nickel(II) complex of a tetradentate (N3O) ligand via a pendant amine substituent",
abstract = "The reactivity of the nickel(II) complex (1) of a tetradentate (N3O) ligand containing a pendant amine group has been demonstrated by reaction with a variety of electrophilic reagents, including iodomethane, acetyl chloride, benzoyl chloride, 4-vinylbenzoyl chloride, acryloyl chloride, toluene-p-sulphonyl chloride, N-acryloylsuccinimide, and the copolymer of N-acryloylsuccinimide and n-butyl acrylate, yielding a series of new complexes. The complex containing a p-vinylbenzoyl substituent group behaved as a comonomer in free-radical-initiated copolymerisation with methyl methacrylate to produce a polymer containing a covalently bound complex. A new fifteen-membered asymmetric macrocyclic complex has been prepared by the self-condensation reaction of complex (1).",
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Peripheral functionalisation of the nickel(II) complex of a tetradentate (N3O) ligand via a pendant amine substituent. / Cameron, James H.; Harvey, Heather B.; Liggat, John J.; Soutar, Ian.

In: Journal of the Chemical Society, Dalton Transactions, No. 7, 1990, p. 2029-2034.

Research output: Contribution to journalArticle

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T1 - Peripheral functionalisation of the nickel(II) complex of a tetradentate (N3O) ligand via a pendant amine substituent

AU - Cameron, James H.

AU - Harvey, Heather B.

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AU - Soutar, Ian

PY - 1990

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