Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum-thallium complex, [MoTl(SC6F 5)4(η-C5H5)]

Jack L. Davidson; Keith Davidson; W. Edward Lindsell

Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum-thallium complex, [MoTl(SC₆F ₅)₄(η-C₅H₅)]

Jack L. Davidson
, Keith Davidson
, W. Edward Lindsell

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Paramagnetic diene complexes [MoX₂(diene)(?-C ₅H₅)] (X = Cl, Br, I, SAr) give well resolved e.s.r. spectra in solution; reaction with TISC₆F₅ produces the unusual fluxional, bimetallic complex [MoTl(SC₆F₅) ₄(?-C₅H₅)].

Original language	English
Pages (from-to)	452-453
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
Publication status	Published - 1983

Cite this

@article{eac72f0b60ab4867809f5c2f8eb92231,

title = "Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum-thallium complex, [MoTl(SC6F 5)4(η-C5H5)]",

abstract = "Paramagnetic diene complexes [MoX2(diene)(?-C 5H5)] (X = Cl, Br, I, SAr) give well resolved e.s.r. spectra in solution; reaction with TISC6F5 produces the unusual fluxional, bimetallic complex [MoTl(SC6F5) 4(?-C5H5)].",

author = "Davidson, \{Jack L.\} and Keith Davidson and Lindsell, \{W. Edward\}",

year = "1983",

language = "English",

pages = "452--453",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "8",

}

TY - JOUR

T1 - Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum-thallium complex, [MoTl(SC6F 5)4(η-C5H5)]

AU - Davidson, Jack L.

AU - Davidson, Keith

AU - Lindsell, W. Edward

PY - 1983

Y1 - 1983

N2 - Paramagnetic diene complexes [MoX2(diene)(?-C 5H5)] (X = Cl, Br, I, SAr) give well resolved e.s.r. spectra in solution; reaction with TISC6F5 produces the unusual fluxional, bimetallic complex [MoTl(SC6F5) 4(?-C5H5)].

AB - Paramagnetic diene complexes [MoX2(diene)(?-C 5H5)] (X = Cl, Br, I, SAr) give well resolved e.s.r. spectra in solution; reaction with TISC6F5 produces the unusual fluxional, bimetallic complex [MoTl(SC6F5) 4(?-C5H5)].

UR - https://www.scopus.com/pages/publications/37049107986

M3 - Article

SN - 0022-4936

SP - 452

EP - 453

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 8

ER -

Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum-thallium complex, [MoTl(SC₆F ₅)₄(η-C₅H₅)]

Abstract

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