Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum-thallium complex, [MoTl(SC6F 5)4(η-C5H5)]

Jack L. Davidson, Keith Davidson, W. Edward Lindsell

Research output: Contribution to journalArticle

Abstract

Paramagnetic diene complexes [MoX2(diene)(?-C 5H5)] (X = Cl, Br, I, SAr) give well resolved e.s.r. spectra in solution; reaction with TISC6F5 produces the unusual fluxional, bimetallic complex [MoTl(SC6F5) 4(?-C5H5)].

Original languageEnglish
Pages (from-to)452-453
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number8
Publication statusPublished - 1983

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