Palladium Promoted Production of Higher Amines from a Lower Amine Feedstock

Yufen Hao; Fernando Cardenas-Lizana; Mark A. Keane

doi:10.1007/s10562-016-1902-7

Palladium Promoted Production of Higher Amines from a Lower Amine Feedstock

Yufen Hao, Fernando Cardenas-Lizana, Mark A. Keane

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Abstract

The catalytic (Pd/Al2O3 and Pd/C; mean Pd size 2.5–3.0 nm from (S)TEM analysis) synthesis of di-butylamine (DBA) and tri-butylamine (TBA) from mono-butylamine (MBA) and DBA, respectively, in continuous gas phase operation is demonstrated. Exclusive production of DBA (from MBA) has been established over both catalysts where 453 ≤ T ≤ 523 K (∆Ea = 79 kJ mol−1). Greater activity for Pd/C is associated with higher levels of surface acidity (from NH3 chemisorption/TPD) and spillover hydrogen (from H2 TPD). Reaction of DBA over both catalysts when configured in series delivered full selectivity to TBA. Our results establish a novel clean alternative route for the continuous production of higher (secondary and tertiary) amines.

Original language	English
Pages (from-to)	803-810
Number of pages	8
Journal	Catalysis Letters
Volume	147
Issue number	4
Early online date	14 Feb 2017
DOIs	https://doi.org/10.1007/s10562-016-1902-7
Publication status	Published - Apr 2017

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title = "Palladium Promoted Production of Higher Amines from a Lower Amine Feedstock",

abstract = "The catalytic (Pd/Al2O3 and Pd/C; mean Pd size 2.5–3.0 nm from (S)TEM analysis) synthesis of di-butylamine (DBA) and tri-butylamine (TBA) from mono-butylamine (MBA) and DBA, respectively, in continuous gas phase operation is demonstrated. Exclusive production of DBA (from MBA) has been established over both catalysts where 453 ≤ T ≤ 523 K (∆Ea = 79 kJ mol−1). Greater activity for Pd/C is associated with higher levels of surface acidity (from NH3 chemisorption/TPD) and spillover hydrogen (from H2 TPD). Reaction of DBA over both catalysts when configured in series delivered full selectivity to TBA. Our results establish a novel clean alternative route for the continuous production of higher (secondary and tertiary) amines.",

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T1 - Palladium Promoted Production of Higher Amines from a Lower Amine Feedstock

AU - Hao, Yufen

AU - Cardenas-Lizana, Fernando

AU - Keane, Mark A.

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Y1 - 2017/4

N2 - The catalytic (Pd/Al2O3 and Pd/C; mean Pd size 2.5–3.0 nm from (S)TEM analysis) synthesis of di-butylamine (DBA) and tri-butylamine (TBA) from mono-butylamine (MBA) and DBA, respectively, in continuous gas phase operation is demonstrated. Exclusive production of DBA (from MBA) has been established over both catalysts where 453 ≤ T ≤ 523 K (∆Ea = 79 kJ mol−1). Greater activity for Pd/C is associated with higher levels of surface acidity (from NH3 chemisorption/TPD) and spillover hydrogen (from H2 TPD). Reaction of DBA over both catalysts when configured in series delivered full selectivity to TBA. Our results establish a novel clean alternative route for the continuous production of higher (secondary and tertiary) amines.

AB - The catalytic (Pd/Al2O3 and Pd/C; mean Pd size 2.5–3.0 nm from (S)TEM analysis) synthesis of di-butylamine (DBA) and tri-butylamine (TBA) from mono-butylamine (MBA) and DBA, respectively, in continuous gas phase operation is demonstrated. Exclusive production of DBA (from MBA) has been established over both catalysts where 453 ≤ T ≤ 523 K (∆Ea = 79 kJ mol−1). Greater activity for Pd/C is associated with higher levels of surface acidity (from NH3 chemisorption/TPD) and spillover hydrogen (from H2 TPD). Reaction of DBA over both catalysts when configured in series delivered full selectivity to TBA. Our results establish a novel clean alternative route for the continuous production of higher (secondary and tertiary) amines.

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VL - 147

SP - 803

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JO - Catalysis Letters

JF - Catalysis Letters

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Palladium Promoted Production of Higher Amines from a Lower Amine Feedstock

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