Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters

Robyn E Fairbairn; Ross McLellan; Ruaraidh D McIntosh; Maria A Palacios; Euan K Brechin; Scott J Dalgarno

doi:10.1039/c3dt53088d

Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters

Robyn E Fairbairn
, Ross McLellan
, Ruaraidh D McIntosh
, Maria A Palacios
, Euan K Brechin
, Scott J Dalgarno

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear Cu-II clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear Cu-II cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.

Original language	English
Pages (from-to)	5292-5298
Number of pages	7
Journal	Dalton Transactions
Volume	43
Issue number	14
DOIs	https://doi.org/10.1039/c3dt53088d
Publication status	Published - 2014

Keywords

CRYSTAL-STRUCTURE
COMPLEXES
CALIXARENE
METAL
GUEST
OXACALIXARENES
MAGNETS
IONS
K+

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10.1039/c3dt53088d

Ruaraidh McIntosh
- R.McIntoshhw.acuk
- School of Engineering & Physical Sciences - Associate Professor
- School of Engineering & Physical Sciences, Institute of Chemical Sciences - Associate Professor
Person: Academic (Research & Teaching)

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title = "Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters",

abstract = "Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear Cu-II clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear Cu-II cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.",

keywords = "CRYSTAL-STRUCTURE, COMPLEXES, CALIXARENE, METAL, GUEST, OXACALIXARENES, MAGNETS, IONS, K+",

author = "Fairbairn, \{Robyn E\} and Ross McLellan and McIntosh, \{Ruaraidh D\} and Palacios, \{Maria A\} and Brechin, \{Euan K\} and Dalgarno, \{Scott J\}",

year = "2014",

doi = "10.1039/c3dt53088d",

language = "English",

volume = "43",

pages = "5292--5298",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "14",

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TY - JOUR

T1 - Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters

AU - Fairbairn, Robyn E

AU - McLellan, Ross

AU - McIntosh, Ruaraidh D

AU - Palacios, Maria A

AU - Brechin, Euan K

AU - Dalgarno, Scott J

PY - 2014

Y1 - 2014

N2 - Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear Cu-II clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear Cu-II cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.

AB - Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear Cu-II clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear Cu-II cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - CALIXARENE

KW - METAL

KW - GUEST

KW - OXACALIXARENES

KW - MAGNETS

KW - IONS

KW - K+

U2 - 10.1039/c3dt53088d

DO - 10.1039/c3dt53088d

M3 - Article

C2 - 24336905

SN - 1477-9226

VL - 43

SP - 5292

EP - 5298

JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters

Abstract

Keywords

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Ruaraidh McIntosh

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