Organocatalyzed carbonyl-olefin metathesis

Research output: Contribution to journalArticle

Abstract

The heat is on: A new [3+2] cycloaddition/cycloreversion strategy allows for catalytic and thermally allowed carbonyl-olefin metathesis (see scheme). This strategy opens opportunities for new developments in the field of carbonyl-olefin metathesis, which traditionally relied on stoichiometric amounts of transition-metal reagents or photochemical promotion.

Original languageEnglish
Pages (from-to)4524-4525
Number of pages2
JournalAngewandte Chemie International Edition
Volume52
Issue number17
Early online date25 Mar 2013
DOIs
Publication statusPublished - 22 Apr 2013

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Keywords

  • alkenes
  • metathesis
  • organocatalysis
  • small rings
  • synthetic methods

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