Optical properties of d3 ions in ligand fields of tetragonal symmetry

H. U. Rahman

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)


The case of an axial ligand field having D4 point symmetry, with OZ as 4-fold axis and the OX, OY axes as 2-fold axes, is considered. Irreducible tensor operators have been used to construct energy matrices of such a noncubic ligand field for the d3 electronic configuration in the 'strong-field' scheme |tn2(S1G1) em(S2G2) SGMs?>. These matrices have been used to analyse the absorption spectrum of trans-Cr(H2O)4F+2. © 1971.

Original languageEnglish
Pages (from-to)256-263
Number of pages8
Issue number2
Publication statusPublished - 28 May 1971


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