Optical properties of d3 ions in ligand fields of tetragonal symmetry

H. U. Rahman

Optical properties of d³ ions in ligand fields of tetragonal symmetry

H. U. Rahman

Research output: Contribution to journal › Article › peer-review

Abstract

The case of an axial ligand field having D₄ point symmetry, with OZ as 4-fold axis and the OX, OY axes as 2-fold axes, is considered. Irreducible tensor operators have been used to construct energy matrices of such a noncubic ligand field for the d³ electronic configuration in the 'strong-field' scheme |tⁿ₂(S₁G₁) e^m(S₂G₂) SGM_s?>. These matrices have been used to analyse the absorption spectrum of trans-Cr(H₂O)₄F⁺₂. © 1971.

Original language	English
Pages (from-to)	256-263
Number of pages	8
Journal	Physica
Volume	53
Issue number	2
Publication status	Published - 28 May 1971

Cite this

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abstract = "The case of an axial ligand field having D4 point symmetry, with OZ as 4-fold axis and the OX, OY axes as 2-fold axes, is considered. Irreducible tensor operators have been used to construct energy matrices of such a noncubic ligand field for the d3 electronic configuration in the 'strong-field' scheme |tn2(S1G1) em(S2G2) SGMs?>. These matrices have been used to analyse the absorption spectrum of trans-Cr(H2O)4F+2. {\textcopyright} 1971.",

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N2 - The case of an axial ligand field having D4 point symmetry, with OZ as 4-fold axis and the OX, OY axes as 2-fold axes, is considered. Irreducible tensor operators have been used to construct energy matrices of such a noncubic ligand field for the d3 electronic configuration in the 'strong-field' scheme |tn2(S1G1) em(S2G2) SGMs?>. These matrices have been used to analyse the absorption spectrum of trans-Cr(H2O)4F+2. © 1971.

AB - The case of an axial ligand field having D4 point symmetry, with OZ as 4-fold axis and the OX, OY axes as 2-fold axes, is considered. Irreducible tensor operators have been used to construct energy matrices of such a noncubic ligand field for the d3 electronic configuration in the 'strong-field' scheme |tn2(S1G1) em(S2G2) SGMs?>. These matrices have been used to analyse the absorption spectrum of trans-Cr(H2O)4F+2. © 1971.

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JO - Physica

JF - Physica

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Optical properties of d³ ions in ligand fields of tetragonal symmetry

Abstract

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