Abstract
Gas-phase photodissociation of CFCl2NO at 147 nm results in the formation of electronically excited NO in the B 2? state, giving rise to the well known NO ß-emission bands. Collisional effects consequent upon the addition of helium lead to the appearance of fluorescence from the NO(A 2?+) state with emission from the ?' = 2 and 3 levels dominating the spectrum. The results are compared with data obtained previously for other nitrosocompounds.
Original language | English |
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Pages (from-to) | 1355-1363 |
Number of pages | 9 |
Journal | Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics |
Volume | 79 |
Issue number | 9 |
DOIs | |
Publication status | Published - 1983 |