NO fluorescence during vacuum-ultraviolet photodissociation of CFCl2NO

C. A F Johnson

Research output: Contribution to journalArticle

Abstract

Gas-phase photodissociation of CFCl2NO at 147 nm results in the formation of electronically excited NO in the B 2? state, giving rise to the well known NO ß-emission bands. Collisional effects consequent upon the addition of helium lead to the appearance of fluorescence from the NO(A 2?+) state with emission from the ?' = 2 and 3 levels dominating the spectrum. The results are compared with data obtained previously for other nitrosocompounds.

Original languageEnglish
Pages (from-to)1355-1363
Number of pages9
JournalJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
Volume79
Issue number9
DOIs
Publication statusPublished - 1983

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