Gas-phase photodissociation of CFCl2NO at 147 nm results in the formation of electronically excited NO in the B 2? state, giving rise to the well known NO ß-emission bands. Collisional effects consequent upon the addition of helium lead to the appearance of fluorescence from the NO(A 2?+) state with emission from the ?' = 2 and 3 levels dominating the spectrum. The results are compared with data obtained previously for other nitrosocompounds.
|Number of pages||9|
|Journal||Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics|
|Publication status||Published - 1983|