Nitrosoarene complexes of rhodium(III), iridium(III), copper(I) and mercury(II). Use of XPS in determining the mode of bonding to transition metals

G. Vasapollo; C. F. Nobile; A. Sacco; B. G. Gowenlock; L. Sabbatini; C. Malitesta; P. G. Zambonin

Nitrosoarene complexes of rhodium(III), iridium(III), copper(I) and mercury(II). Use of XPS in determining the mode of bonding to transition metals

G. Vasapollo, C. F. Nobile, A. Sacco, B. G. Gowenlock, L. Sabbatini, C. Malitesta, P. G. Zambonin

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Some previously synthesized nitrosoarene complexes of known coordination mode have been studied by XPS spectroscopy. New nitrosoarene complexes of Rh^III, Ir^III, Cu^I and Hg^II have been synthesized and studied by both X-ray photoelectron and IR spectroscopy. A correlation was found between the value ?E_B(O-N) and the bonding mode of the nitroso ligand. © 1989.

Original language	English
Pages (from-to)	239-244
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	378
Issue number	2
Publication status	Published - 5 Dec 1989

Cite this

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abstract = "Some previously synthesized nitrosoarene complexes of known coordination mode have been studied by XPS spectroscopy. New nitrosoarene complexes of RhIII, IrIII, CuI and HgII have been synthesized and studied by both X-ray photoelectron and IR spectroscopy. A correlation was found between the value ?EB(O-N) and the bonding mode of the nitroso ligand. {\textcopyright} 1989.",

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AU - Vasapollo, G.

AU - Nobile, C. F.

AU - Sacco, A.

AU - Gowenlock, B. G.

AU - Sabbatini, L.

AU - Malitesta, C.

AU - Zambonin, P. G.

PY - 1989/12/5

Y1 - 1989/12/5

N2 - Some previously synthesized nitrosoarene complexes of known coordination mode have been studied by XPS spectroscopy. New nitrosoarene complexes of RhIII, IrIII, CuI and HgII have been synthesized and studied by both X-ray photoelectron and IR spectroscopy. A correlation was found between the value ?EB(O-N) and the bonding mode of the nitroso ligand. © 1989.

AB - Some previously synthesized nitrosoarene complexes of known coordination mode have been studied by XPS spectroscopy. New nitrosoarene complexes of RhIII, IrIII, CuI and HgII have been synthesized and studied by both X-ray photoelectron and IR spectroscopy. A correlation was found between the value ?EB(O-N) and the bonding mode of the nitroso ligand. © 1989.

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M3 - Article

SN - 0022-328X

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JF - Journal of Organometallic Chemistry

IS - 2

ER -

Nitrosoarene complexes of rhodium(III), iridium(III), copper(I) and mercury(II). Use of XPS in determining the mode of bonding to transition metals

Abstract

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