Nitrosoarene complexes of rhodium(III), iridium(III), copper(I) and mercury(II). Use of XPS in determining the mode of bonding to transition metals

G. Vasapollo, C. F. Nobile, A. Sacco, B. G. Gowenlock, L. Sabbatini, C. Malitesta, P. G. Zambonin

Research output: Contribution to journalArticlepeer-review

Abstract

Some previously synthesized nitrosoarene complexes of known coordination mode have been studied by XPS spectroscopy. New nitrosoarene complexes of RhIII, IrIII, CuI and HgII have been synthesized and studied by both X-ray photoelectron and IR spectroscopy. A correlation was found between the value ?EB(O-N) and the bonding mode of the nitroso ligand. © 1989.

Original languageEnglish
Pages (from-to)239-244
Number of pages6
JournalJournal of Organometallic Chemistry
Volume378
Issue number2
Publication statusPublished - 5 Dec 1989

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