NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE

D R  ADAMS; W  CARRUTHERS; P J  CROWLEY

NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE

D R ADAMS, W CARRUTHERS, P J CROWLEY

Research output: Contribution to journal › Article › peer-review

Abstract

Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.

Original language	English
Pages (from-to)	1261-1263
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
Publication status	Published - 15 Sept 1991

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title = "NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE",

abstract = "Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.",

author = "ADAMS, \{D R\} and W CARRUTHERS and CROWLEY, \{P J\}",

year = "1991",

month = sep,

day = "15",

language = "English",

pages = "1261--1263",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "18",

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T1 - NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE

AU - ADAMS, D R

AU - CARRUTHERS, W

AU - CROWLEY, P J

PY - 1991/9/15

Y1 - 1991/9/15

N2 - Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.

AB - Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.

M3 - Article

SN - 0022-4936

SP - 1261

EP - 1263

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 18

ER -

NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE

Abstract

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