NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE

D R ADAMS, W CARRUTHERS, P J CROWLEY

Research output: Contribution to journalArticle

Abstract

Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.

Original languageEnglish
Pages (from-to)1261-1263
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number18
Publication statusPublished - 15 Sep 1991

Cite this

@article{868c72e3eaf54aacbe5a35aede9788a3,
title = "NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE",
abstract = "Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.",
author = "ADAMS, {D R} and W CARRUTHERS and CROWLEY, {P J}",
year = "1991",
month = "9",
day = "15",
language = "English",
pages = "1261--1263",
journal = "Journal of the Chemical Society, Chemical Communications",
issn = "0022-4936",
publisher = "Chemical Society",
number = "18",

}

NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE. / ADAMS, D R ; CARRUTHERS, W ; CROWLEY, P J .

In: Journal of the Chemical Society, Chemical Communications, No. 18, 15.09.1991, p. 1261-1263.

Research output: Contribution to journalArticle

TY - JOUR

T1 - NITRONE CYCLOADDITION-BASED ENTRY TO THE COCCINELLINE ALKALOID SKELETON - SYNTHESIS OF (+/-)-EPI-HIPPODAMINE

AU - ADAMS, D R

AU - CARRUTHERS, W

AU - CROWLEY, P J

PY - 1991/9/15

Y1 - 1991/9/15

N2 - Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.

AB - Synthesis of intermediate 13 possessing the perhydropyrido[2,1,6-de]quinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.

M3 - Article

SP - 1261

EP - 1263

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

IS - 18

ER -