TY - JOUR
T1 - New routes to η7-cycloheptatrienylmolybdenum complexes: Crystal and molecular structures of [Mo(acac)(H2O)(η7- C7H7)]+BF4- and [Mo(NCS)(acac)(η7-C7H7)]
AU - Bochmann, Manfred
AU - Cooke, Michael
AU - Green, Michael
AU - Kirsch, Howard P.
AU - Stone, F. Gordon A.
AU - Welch, Alan J.
PY - 1976
Y1 - 1976
N2 - Reaction of [Mo(CO)3(η7-C7H 7)]BF4 with arenes gives [Mo(η7-C 7H7)(η6-arene)]BF4, whereas the halides Me3SiX (X = Cl, Br, or I) form [Mo2X 3(η7-C7H7)2], the latter being reversibly oxidised to binuclear monocations; treatment of the mononuclear cations with acacH affords [Mo(acac)(H2O) (η7-C7H7)]+, which with anions (X-) yields the neutral species [MoX(acac)(η7-C 7H7)], both these paramagnetic complexes being structurally characterised by X-ray crystallography.
AB - Reaction of [Mo(CO)3(η7-C7H 7)]BF4 with arenes gives [Mo(η7-C 7H7)(η6-arene)]BF4, whereas the halides Me3SiX (X = Cl, Br, or I) form [Mo2X 3(η7-C7H7)2], the latter being reversibly oxidised to binuclear monocations; treatment of the mononuclear cations with acacH affords [Mo(acac)(H2O) (η7-C7H7)]+, which with anions (X-) yields the neutral species [MoX(acac)(η7-C 7H7)], both these paramagnetic complexes being structurally characterised by X-ray crystallography.
UR - http://www.scopus.com/inward/record.url?scp=37049098463&partnerID=8YFLogxK
U2 - 10.1039/C39760000381
DO - 10.1039/C39760000381
M3 - Article
AN - SCOPUS:37049098463
SN - 0022-4936
SP - 381
EP - 383
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 11
ER -