Abstract
Conductivities in a number of polymer electrolyte systems have been investigated using divalent cation salts such as Mg(ClO4)2, Ca(ClO4)2, Ni(ClO4)2 and ZnCl2. The polymers used were comb-branched structures with oligo(ethylene oxide) and oligo(propylene oxide) side chains and polyphosphazene networks linked by tetra-aza-macrocyles. The systems using Mg and Ca salts achieved levels as high as 10-3-10-4 S cm-1 but the aza-macrocycles were about two orders of magnitude poorer. © 1992.
Original language | English |
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Pages (from-to) | 1539-1544 |
Number of pages | 6 |
Journal | Electrochimica Acta |
Volume | 37 |
Issue number | 9 |
Publication status | Published - Jan 1992 |
Keywords
- aza-macrocyles
- comb-branch polymers
- divalent cation salts
- ion conduction
- polymer electrolytes