New Coordination Polymers with Extended Arm Cyclotriguaiacyclene Ligands: 1D chains, and interpenetrating or polycatenating 2D (42.6 2)(4.62)2 networks

Marc A. Little; Tanya K. Ronson; Michaele J. Hardie

doi:10.1039/c1dt10662g

New Coordination Polymers with Extended Arm Cyclotriguaiacyclene Ligands: 1D chains, and interpenetrating or polycatenating 2D (4².6 ²)(4.6²)₂ networks

Marc A. Little, Tanya K. Ronson, Michaele J. Hardie^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A series of new 1D chain and 2D coordination polymers with cyclotriguaiacylene-type ligands are reported. A zig-zag 1D coordination chain is found in complex [Cd₂(4ph4py)(NO₃)₃(H ₂O)₂(DMA)₂]·(NO₃) ·(DMA)₄, where 4ph4py = tris[4-(4-pyridyl)benzoyl]- cyclotriguaiacylene and DMA = dimethylacetamide, while complex [Zn(4ph4py) ₂(CF₃COO)(H₂O)]·(CF₃COO)(NMP) ₇, where NMP = N-methylpyrrolidone, has a doubly bridged coordination chain structure. Complexes [M(3ph3py)(NO₃)₂]·(NMP) ₄ where M = Co or Zn, 3ph3py = tris[3-(3-pyridyl)benzoyl] cyclotriguaiacylene, are isostructural and feature 1D ladder coordination chains. Complexes [Cd₂(4ph4py)₂(NO₃) ₄(NMP)]·(NMP)₉(H₂O)₄ and [Co(4ph4py)(H₂O)₂]·(NO₃) ₂·(DMF)₂, where DMF = dimethylformamide, both have (3,4)-connected 2D coordination polymers with a rare (4².6 ²)(4.6²)₂ topology. A 2D coordination polymer with this topology is also found in complex [Co₂(3ph4py) ₂(NO₃)(H₂O)₅]·(NO ₃)₃·(DMF)₉ where 3ph4py = tris[3-(4-pyridyl)benzoyl]cyclotriguaiacylene. All 2D coordination polymer complexes are interpenetrating or polycatenating. [Co₂(3ph4py) ₂(NO₃)(H₂O)₅]³⁺polymers form a 2D→3D polycatenation showing self-complementary "hand- shake" interactions between the host-type ligands.

Original language	English
Pages (from-to)	12217-12227
Number of pages	11
Journal	Dalton Transactions
Volume	40
Issue number	45
DOIs	https://doi.org/10.1039/c1dt10662g
Publication status	Published - 7 Dec 2011

ASJC Scopus subject areas

Inorganic Chemistry

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@article{fcdf652b91344564882463c6660a9b08,

title = "New Coordination Polymers with Extended Arm Cyclotriguaiacyclene Ligands: 1D chains, and interpenetrating or polycatenating 2D (42.6 2)(4.62)2 networks",

abstract = "A series of new 1D chain and 2D coordination polymers with cyclotriguaiacylene-type ligands are reported. A zig-zag 1D coordination chain is found in complex [Cd2(4ph4py)(NO3)3(H 2O)2(DMA)2]·(NO3) ·(DMA)4, where 4ph4py = tris[4-(4-pyridyl)benzoyl]- cyclotriguaiacylene and DMA = dimethylacetamide, while complex [Zn(4ph4py) 2(CF3COO)(H2O)]·(CF3COO)(NMP) 7, where NMP = N-methylpyrrolidone, has a doubly bridged coordination chain structure. Complexes [M(3ph3py)(NO3)2]·(NMP) 4 where M = Co or Zn, 3ph3py = tris[3-(3-pyridyl)benzoyl] cyclotriguaiacylene, are isostructural and feature 1D ladder coordination chains. Complexes [Cd2(4ph4py)2(NO3) 4(NMP)]·(NMP)9(H2O)4 and [Co(4ph4py)(H2O)2]·(NO3) 2·(DMF)2, where DMF = dimethylformamide, both have (3,4)-connected 2D coordination polymers with a rare (42.6 2)(4.62)2 topology. A 2D coordination polymer with this topology is also found in complex [Co2(3ph4py) 2(NO3)(H2O)5]·(NO 3)3·(DMF)9 where 3ph4py = tris[3-(4-pyridyl)benzoyl]cyclotriguaiacylene. All 2D coordination polymer complexes are interpenetrating or polycatenating. [Co2(3ph4py) 2(NO3)(H2O)5]3+polymers form a 2D→3D polycatenation showing self-complementary {"}hand- shake{"} interactions between the host-type ligands.",

author = "Little, {Marc A.} and Ronson, {Tanya K.} and Hardie, {Michaele J.}",

year = "2011",

month = dec,

day = "7",

doi = "10.1039/c1dt10662g",

language = "English",

volume = "40",

pages = "12217--12227",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T2 - 1D chains, and interpenetrating or polycatenating 2D (42.6 2)(4.62)2 networks

AU - Little, Marc A.

AU - Ronson, Tanya K.

AU - Hardie, Michaele J.

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N2 - A series of new 1D chain and 2D coordination polymers with cyclotriguaiacylene-type ligands are reported. A zig-zag 1D coordination chain is found in complex [Cd2(4ph4py)(NO3)3(H 2O)2(DMA)2]·(NO3) ·(DMA)4, where 4ph4py = tris[4-(4-pyridyl)benzoyl]- cyclotriguaiacylene and DMA = dimethylacetamide, while complex [Zn(4ph4py) 2(CF3COO)(H2O)]·(CF3COO)(NMP) 7, where NMP = N-methylpyrrolidone, has a doubly bridged coordination chain structure. Complexes [M(3ph3py)(NO3)2]·(NMP) 4 where M = Co or Zn, 3ph3py = tris[3-(3-pyridyl)benzoyl] cyclotriguaiacylene, are isostructural and feature 1D ladder coordination chains. Complexes [Cd2(4ph4py)2(NO3) 4(NMP)]·(NMP)9(H2O)4 and [Co(4ph4py)(H2O)2]·(NO3) 2·(DMF)2, where DMF = dimethylformamide, both have (3,4)-connected 2D coordination polymers with a rare (42.6 2)(4.62)2 topology. A 2D coordination polymer with this topology is also found in complex [Co2(3ph4py) 2(NO3)(H2O)5]·(NO 3)3·(DMF)9 where 3ph4py = tris[3-(4-pyridyl)benzoyl]cyclotriguaiacylene. All 2D coordination polymer complexes are interpenetrating or polycatenating. [Co2(3ph4py) 2(NO3)(H2O)5]3+polymers form a 2D→3D polycatenation showing self-complementary "hand- shake" interactions between the host-type ligands.

AB - A series of new 1D chain and 2D coordination polymers with cyclotriguaiacylene-type ligands are reported. A zig-zag 1D coordination chain is found in complex [Cd2(4ph4py)(NO3)3(H 2O)2(DMA)2]·(NO3) ·(DMA)4, where 4ph4py = tris[4-(4-pyridyl)benzoyl]- cyclotriguaiacylene and DMA = dimethylacetamide, while complex [Zn(4ph4py) 2(CF3COO)(H2O)]·(CF3COO)(NMP) 7, where NMP = N-methylpyrrolidone, has a doubly bridged coordination chain structure. Complexes [M(3ph3py)(NO3)2]·(NMP) 4 where M = Co or Zn, 3ph3py = tris[3-(3-pyridyl)benzoyl] cyclotriguaiacylene, are isostructural and feature 1D ladder coordination chains. Complexes [Cd2(4ph4py)2(NO3) 4(NMP)]·(NMP)9(H2O)4 and [Co(4ph4py)(H2O)2]·(NO3) 2·(DMF)2, where DMF = dimethylformamide, both have (3,4)-connected 2D coordination polymers with a rare (42.6 2)(4.62)2 topology. A 2D coordination polymer with this topology is also found in complex [Co2(3ph4py) 2(NO3)(H2O)5]·(NO 3)3·(DMF)9 where 3ph4py = tris[3-(4-pyridyl)benzoyl]cyclotriguaiacylene. All 2D coordination polymer complexes are interpenetrating or polycatenating. [Co2(3ph4py) 2(NO3)(H2O)5]3+polymers form a 2D→3D polycatenation showing self-complementary "hand- shake" interactions between the host-type ligands.

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SN - 1477-9226

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New Coordination Polymers with Extended Arm Cyclotriguaiacyclene Ligands: 1D chains, and interpenetrating or polycatenating 2D (4².6 ²)(4.6²)₂ networks

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