Monofunctionalised cucurbit[6]uril synthesis using imidazolium host-guest complexation

Nan Zhao; Gareth O Lloyd; Oren A Scherman

doi:10.1039/c2cc17433b

Monofunctionalised cucurbit[6]uril synthesis using imidazolium host-guest complexation

Nan Zhao, Gareth O Lloyd, Oren A Scherman

Research output: Contribution to journal › Article › peer-review

109 Citations (Scopus)

Abstract

Monohydroxylated cucurbit[6]uril was prepared for the first time through the controlled oxidation of CB[6] in the presence of a tailor-made bisimidazolium guest, as verified by H-1 NMR, ESI-MS and X-ray crystallography. Further chemical modification of monohydroxylated CB[6] was also readily achieved.

Original language	English
Pages (from-to)	3070-3072
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	25
DOIs	https://doi.org/10.1039/c2cc17433b
Publication status	Published - 2012

Keywords

AQUEOUS-SOLUTION
IONIC LIQUIDS
CYCLODEXTRIN
BINDING
DERIVATIVES
CUCURBITURIL
ARCHITECTURE
SELECTIVITY
MONOLAYERS
MOLECULES

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10.1039/c2cc17433b

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title = "Monofunctionalised cucurbit[6]uril synthesis using imidazolium host-guest complexation",

abstract = "Monohydroxylated cucurbit[6]uril was prepared for the first time through the controlled oxidation of CB[6] in the presence of a tailor-made bisimidazolium guest, as verified by H-1 NMR, ESI-MS and X-ray crystallography. Further chemical modification of monohydroxylated CB[6] was also readily achieved.",

keywords = "AQUEOUS-SOLUTION, IONIC LIQUIDS, CYCLODEXTRIN, BINDING, DERIVATIVES, CUCURBITURIL, ARCHITECTURE, SELECTIVITY, MONOLAYERS, MOLECULES",

author = "Nan Zhao and Lloyd, {Gareth O} and Scherman, {Oren A}",

year = "2012",

doi = "10.1039/c2cc17433b",

language = "English",

volume = "48",

pages = "3070--3072",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Monofunctionalised cucurbit[6]uril synthesis using imidazolium host-guest complexation

AU - Zhao, Nan

AU - Lloyd, Gareth O

AU - Scherman, Oren A

PY - 2012

Y1 - 2012

N2 - Monohydroxylated cucurbit[6]uril was prepared for the first time through the controlled oxidation of CB[6] in the presence of a tailor-made bisimidazolium guest, as verified by H-1 NMR, ESI-MS and X-ray crystallography. Further chemical modification of monohydroxylated CB[6] was also readily achieved.

AB - Monohydroxylated cucurbit[6]uril was prepared for the first time through the controlled oxidation of CB[6] in the presence of a tailor-made bisimidazolium guest, as verified by H-1 NMR, ESI-MS and X-ray crystallography. Further chemical modification of monohydroxylated CB[6] was also readily achieved.

KW - AQUEOUS-SOLUTION

KW - IONIC LIQUIDS

KW - CYCLODEXTRIN

KW - BINDING

KW - DERIVATIVES

KW - CUCURBITURIL

KW - ARCHITECTURE

KW - SELECTIVITY

KW - MONOLAYERS

KW - MOLECULES

U2 - 10.1039/c2cc17433b

DO - 10.1039/c2cc17433b

M3 - Article

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SN - 1359-7345

VL - 48

SP - 3070

EP - 3072

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

Monofunctionalised cucurbit[6]uril synthesis using imidazolium host-guest complexation

Abstract

Keywords

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