Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

Leslie D. Field; Alison M. Magill; Timothy K. Shearer; Scott J. Dalgarno; Peter Turner

doi:10.1021/om7004063

Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

Leslie D. Field
, Alison M. Magill
, Timothy K. Shearer
, Scott J. Dalgarno
, Peter Turner

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).

Original language	English
Pages (from-to)	4776-4780
Number of pages	5
Journal	Organometallics
Volume	26
Issue number	19
DOIs	https://doi.org/10.1021/om7004063
Publication status	Published - 10 Sept 2007

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title = "Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes",

abstract = "Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).",

author = "Field, \{Leslie D.\} and Magill, \{Alison M.\} and Shearer, \{Timothy K.\} and Dalgarno, \{Scott J.\} and Peter Turner",

year = "2007",

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doi = "10.1021/om7004063",

language = "English",

volume = "26",

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journal = "Organometallics",

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T1 - Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

AU - Field, Leslie D.

AU - Magill, Alison M.

AU - Shearer, Timothy K.

AU - Dalgarno, Scott J.

AU - Turner, Peter

PY - 2007/9/10

Y1 - 2007/9/10

N2 - Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).

AB - Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).

U2 - 10.1021/om7004063

DO - 10.1021/om7004063

M3 - Article

SN - 0276-7333

VL - 26

SP - 4776

EP - 4780

JO - Organometallics

JF - Organometallics

IS - 19

ER -

Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

Abstract

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