Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

Leslie D. Field; Alison M. Magill; Timothy K. Shearer; Scott J. Dalgarno; Peter Turner

doi:10.1021/om7004063

Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

Leslie D. Field, Alison M. Magill, Timothy K. Shearer, Scott J. Dalgarno, Peter Turner

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).

Original language	English
Pages (from-to)	4776-4780
Number of pages	5
Journal	Organometallics
Volume	26
Issue number	19
DOIs	https://doi.org/10.1021/om7004063
Publication status	Published - 10 Sept 2007

Access to Document

10.1021/om7004063

Cite this

@article{8a075c23917e425c84eae036c54a4100,

title = "Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes",

abstract = "Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).",

author = "Field, {Leslie D.} and Magill, {Alison M.} and Shearer, {Timothy K.} and Dalgarno, {Scott J.} and Peter Turner",

year = "2007",

month = sep,

day = "10",

doi = "10.1021/om7004063",

language = "English",

volume = "26",

pages = "4776--4780",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

AU - Field, Leslie D.

AU - Magill, Alison M.

AU - Shearer, Timothy K.

AU - Dalgarno, Scott J.

AU - Turner, Peter

PY - 2007/9/10

Y1 - 2007/9/10

N2 - Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).

AB - Acetylido methyl ruthenium(II) complexes, trans-Ru(C CR)(CH3)(dmpe)(2), were synthesized in a single metathesis reaction from trans-Ru(CH3)2(dmpe)2 at ambient temperature; at elevated temperatures the reaction yields trans-Ru(C CR)(2)(dmpe)(2). Addition of a second terminal acetylene to a methanol solution of trans-Ru(C CR)(CH3)(dmpe)(2) results in the formation of trans-Ru(C CR)(C CR')(dmpe)(2).

U2 - 10.1021/om7004063

DO - 10.1021/om7004063

M3 - Article

SN - 0276-7333

VL - 26

SP - 4776

EP - 4780

JO - Organometallics

JF - Organometallics

IS - 19

ER -

Mono- and Bis-acetylidoruthenium(II) complexes by controlled metathesis of methylruthenium complexes with acetylenes

Abstract

Access to Document

Fingerprint

Cite this