Molecular paneling in the rational design of calixarene coordination polymers

Piotr P Cholewa; Christine M Beavers; Simon J Teat; Scott J Dalgarno

doi:10.1021/cg400125x

Molecular paneling in the rational design of calixarene coordination polymers

Piotr P Cholewa
, Christine M Beavers
, Simon J Teat
, Scott J Dalgarno

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

We demonstrate the design of calixarene coordination polymers by using versatile molecular panels comprising binuclear Co(II) clusters and p-carboxylatocalix-[4]arenes linked together with 4,4'-bipyridyls. By variation in the length of the 4,4'-bipyridyl, conformational changes in the calixarene molecule have been observed and the solvent-filled channels within the crystalline solid have been adjusted.

Original language	English
Pages (from-to)	2703-2706
Number of pages	4
Journal	Crystal Growth and Design
Volume	13
Issue number	7
DOIs	https://doi.org/10.1021/cg400125x
Publication status	Published - 3 Jul 2013

Keywords

SUPRAMOLECULAR COMPOUNDS
NANOTUBES
ABSORPTION
COMPLEXES
CRYSTALS
HYDROGEN
METHANE
SOLIDS

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10.1021/cg400125x

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title = "Molecular paneling in the rational design of calixarene coordination polymers",

abstract = "We demonstrate the design of calixarene coordination polymers by using versatile molecular panels comprising binuclear Co(II) clusters and p-carboxylatocalix-[4]arenes linked together with 4,4'-bipyridyls. By variation in the length of the 4,4'-bipyridyl, conformational changes in the calixarene molecule have been observed and the solvent-filled channels within the crystalline solid have been adjusted.",

keywords = "SUPRAMOLECULAR COMPOUNDS, NANOTUBES, ABSORPTION, COMPLEXES, CRYSTALS, HYDROGEN, METHANE, SOLIDS",

author = "Cholewa, \{Piotr P\} and Beavers, \{Christine M\} and Teat, \{Simon J\} and Dalgarno, \{Scott J\}",

year = "2013",

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doi = "10.1021/cg400125x",

language = "English",

volume = "13",

pages = "2703--2706",

journal = "Crystal Growth and Design",

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TY - JOUR

T1 - Molecular paneling in the rational design of calixarene coordination polymers

AU - Cholewa, Piotr P

AU - Beavers, Christine M

AU - Teat, Simon J

AU - Dalgarno, Scott J

PY - 2013/7/3

Y1 - 2013/7/3

N2 - We demonstrate the design of calixarene coordination polymers by using versatile molecular panels comprising binuclear Co(II) clusters and p-carboxylatocalix-[4]arenes linked together with 4,4'-bipyridyls. By variation in the length of the 4,4'-bipyridyl, conformational changes in the calixarene molecule have been observed and the solvent-filled channels within the crystalline solid have been adjusted.

AB - We demonstrate the design of calixarene coordination polymers by using versatile molecular panels comprising binuclear Co(II) clusters and p-carboxylatocalix-[4]arenes linked together with 4,4'-bipyridyls. By variation in the length of the 4,4'-bipyridyl, conformational changes in the calixarene molecule have been observed and the solvent-filled channels within the crystalline solid have been adjusted.

KW - SUPRAMOLECULAR COMPOUNDS

KW - NANOTUBES

KW - ABSORPTION

KW - COMPLEXES

KW - CRYSTALS

KW - HYDROGEN

KW - METHANE

KW - SOLIDS

U2 - 10.1021/cg400125x

DO - 10.1021/cg400125x

M3 - Article

SN - 1528-7483

VL - 13

SP - 2703

EP - 2706

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 7

ER -

Molecular paneling in the rational design of calixarene coordination polymers

Abstract

Keywords

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