Microfluidic synthesis of high-performance monodispersed chitosan microparticles for methyl orange adsorption

Zheng Dong, Hong Xu, Zhishan Bai, Huizhi Wang, Xiaojiao Luo, Li Zhang, Zhiyong Tang, Rafael Luque, Jin Xuan

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16 Citations (Scopus)
81 Downloads (Pure)

Abstract

High-performance monodispersed chitosan microparticles for methyl orange (MO) adsorption were synthesized on a microfluidic platform coupled with cross-linking approach. Batch adsorption experiments were carried out to evaluate the capacity and kinetics of the as-prepared microparticles on the adsorption of MO. Due to the advantage of microfluidics that all the manipulation and operations are related to independent droplets, the prepared microparticles are controlled to within a narrow size distribution (CV=1.86%) while exhibiting uniform high performance (adsorption capacity=182 mg/g). Adsorption experiments were carried out under various design and operation conditions. It is found that the adsorption isotherm was well described by the Langmuir model and the adsorption kinetics followed a pseudo-second-order kinetic model. The high performance together with biodegradable feature and low-cost raw material give the microfluidic-synthesized chitosan microparticles a promising potential for future dye effluent treatment.
Original languageEnglish
Pages (from-to)78352-78360
Number of pages9
JournalRSC Advances
Volume5
Issue number95
Early online date4 Sep 2015
DOIs
Publication statusPublished - 2015

Keywords

  • WASTE-WATER TREATMENT
  • CARBON NANOTUBES
  • AQUEOUS-SOLUTION
  • DYE ADSORPTION
  • METAL-IONS
  • AZO-DYE
  • EQUILIBRIUM
  • REMOVAL
  • THERMODYNAMICS
  • KINETICS

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  • Cite this

    Dong, Z., Xu, H., Bai, Z., Wang, H., Luo, X., Zhang, L., Tang, Z., Luque, R., & Xuan, J. (2015). Microfluidic synthesis of high-performance monodispersed chitosan microparticles for methyl orange adsorption. RSC Advances, 5(95), 78352-78360. https://doi.org/10.1039/C5RA17226H