Methylammonium antimony sulfide

R. J E Lees; Anthony V. Powell; Ann M. Chippindale

doi:10.1107/S0108270105032361

Methylammonium antimony sulfide

R. J E Lees, Anthony V. Powell, Ann M. Chippindale

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH ₃NH₃)₂[Sb₈S₁₂(S ₂)], contains pairs of [Sb₄S₇]^2- chains joined through an unusual persulflde bond to create infinite double [Sb₈S₁₄]^2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb₈S₁₀) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

Original language	English
Pages (from-to)	m516-m518
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	61
Issue number	12
DOIs	https://doi.org/10.1107/S0108270105032361
Publication status	Published - Dec 2005

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title = "Methylammonium antimony sulfide",

abstract = "Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. {\textcopyright} 2005 International Union of Crystallography.",

author = "Lees, {R. J E} and Powell, {Anthony V.} and Chippindale, {Ann M.}",

year = "2005",

month = dec,

doi = "10.1107/S0108270105032361",

language = "English",

volume = "61",

pages = "m516--m518",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Methylammonium antimony sulfide

AU - Lees, R. J E

AU - Powell, Anthony V.

AU - Chippindale, Ann M.

PY - 2005/12

Y1 - 2005/12

N2 - Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

AB - Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

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U2 - 10.1107/S0108270105032361

DO - 10.1107/S0108270105032361

M3 - Article

VL - 61

SP - m516-m518

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 12

ER -

Methylammonium antimony sulfide

Abstract

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