Methylammonium antimony sulfide

R. J E Lees, Anthony V. Powell, Ann M. Chippindale

Research output: Contribution to journalArticle

Abstract

Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

Original languageEnglish
Pages (from-to)m516-m518
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number12
DOIs
Publication statusPublished - Dec 2005

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Antimony
Sulfides
Diamines
Crystallography
Cations
Decomposition
methylamine

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Lees, R. J E ; Powell, Anthony V. ; Chippindale, Ann M. / Methylammonium antimony sulfide. In: Acta Crystallographica Section C: Crystal Structure Communications. 2005 ; Vol. 61, No. 12. pp. m516-m518.
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Methylammonium antimony sulfide. / Lees, R. J E; Powell, Anthony V.; Chippindale, Ann M.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 12, 12.2005, p. m516-m518.

Research output: Contribution to journalArticle

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AB - Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

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