Abstract
Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.
| Original language | English |
|---|---|
| Pages (from-to) | m516-m518 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 61 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - Dec 2005 |
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Methylammonium antimony sulfide. / Lees, R. J E; Powell, Anthony V.; Chippindale, Ann M.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 12, 12.2005, p. m516-m518.Research output: Contribution to journal › Article
TY - JOUR
T1 - Methylammonium antimony sulfide
AU - Lees, R. J E
AU - Powell, Anthony V.
AU - Chippindale, Ann M.
PY - 2005/12
Y1 - 2005/12
N2 - Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.
AB - Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.
UR - http://www.scopus.com/inward/record.url?scp=30744438354&partnerID=8YFLogxK
U2 - 10.1107/S0108270105032361
DO - 10.1107/S0108270105032361
M3 - Article
VL - 61
SP - m516-m518
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 12
ER -