Methylammonium antimony sulfide

R. J E Lees, Anthony V. Powell, Ann M. Chippindale

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

Original languageEnglish
Pages (from-to)m516-m518
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number12
DOIs
Publication statusPublished - Dec 2005

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