Methylammonium antimony sulfide

R. J E Lees; Anthony V. Powell; Ann M. Chippindale

doi:10.1107/S0108270105032361

Methylammonium antimony sulfide

R. J E Lees, Anthony V. Powell, Ann M. Chippindale

Research output: Contribution to journal › Article

Abstract

Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH ₃NH₃)₂[Sb₈S₁₂(S ₂)], contains pairs of [Sb₄S₇]^2- chains joined through an unusual persulflde bond to create infinite double [Sb₈S₁₄]^2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb₈S₁₀) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

Original language	English
Pages (from-to)	m516-m518
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	61
Issue number	12
DOIs	https://doi.org/10.1107/S0108270105032361
Publication status	Published - Dec 2005

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Lees, R. J. E., Powell, A. V., & Chippindale, A. M. (2005). Methylammonium antimony sulfide. Acta Crystallographica Section C: Crystal Structure Communications, 61(12), m516-m518. https://doi.org/10.1107/S0108270105032361

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title = "Methylammonium antimony sulfide",

abstract = "Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. {\textcopyright} 2005 International Union of Crystallography.",

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AU - Powell, Anthony V.

AU - Chippindale, Ann M.

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N2 - Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

AB - Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb?S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.

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DO - 10.1107/S0108270105032361

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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