Metallaborane chemistry. Part 11. Lower rotational barriers in seven-vertex than in twelve-vertex carbaplatinaboranes: synthesis, and molecular and crystal structures of [closo-1,1-(Et3P)2-2,3-Me2-1,2,3-PtC2B4H4] and [closo-1,1-(Et3P)2-1,2,4-PtC2B4H6]

Geoffrey K. Barker, Michael Green, F. Gordon A. Stone, Alan J. Welch

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Dive into the research topics of 'Metallaborane chemistry. Part 11. Lower rotational barriers in seven-vertex than in twelve-vertex carbaplatinaboranes: synthesis, and molecular and crystal structures of [closo-1,1-(Et<sub>3</sub>P)<sub>2</sub>-2,3-Me<sub>2</sub>-1,2,3-PtC<sub>2</sub>B<sub>4</sub>H<sub>4</sub>] and [closo-1,1-(Et<sub>3</sub>P)<sub>2</sub>-1,2,4-PtC<sub>2</sub>B<sub>4</sub>H<sub>6</sub>]'. Together they form a unique fingerprint.

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