Metallaborane chemistry. Part 10. Insertion of zerovalent platinum species into bridging boron-hydrogen-boron bonds of 2,3-dicarba-nido-hexaborane(8), 2,3-dimethyl-2,3-dicarba-nido-hexaborane(8), and monocarba-nido-hexaborane(9); Molecular and crystal structure of [nido-μ4,5-{trans-(Et3P)2Pt(H)}-μ 5,6-H-2,3-C2B4H6]

Geoffrey K. Barker, Michael Green, F. Gordon A. Stone*, Alan J. Welch, Thomas P. Onak, Gowit Siwapanyoyos

*Corresponding author for this work

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Dive into the research topics of 'Metallaborane chemistry. Part 10. Insertion of zerovalent platinum species into bridging boron-hydrogen-boron bonds of 2,3-dicarba-nido-hexaborane(8), 2,3-dimethyl-2,3-dicarba-nido-hexaborane(8), and monocarba-nido-hexaborane(9); Molecular and crystal structure of [nido-μ4,5-{trans-(Et3P)2Pt(H)}-μ 5,6-H-2,3-C2B4H6]'. Together they form a unique fingerprint.

Chemical Compounds