Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{η3-C(CF3)C(CF 3)C(Me)=C(Ph)SPri}(CF3C≡CCF 3)(η5-C5H5)], [WSPr i{η5-C(CF3)C(CF3)C(CF 3)=C(CF3)C(Me)=C(Ph)...

Naz M. Agh-Atabay; Jack L. Davidson; Graeme Douglas; Kenneth W. Muir

doi:10.1039/C39890000549

Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{η³-C(CF₃)C(CF ₃)C(Me)=C(Ph)SPrⁱ}(CF₃C≡CCF ₃)(η⁵-C₅H₅)], [WSPr ⁱ{η⁵-C(CF₃)C(CF₃)C(CF ₃)=C(CF₃)C(Me)=C(Ph)...

Naz M. Agh-Atabay, Jack L. Davidson, Graeme Douglas, Kenneth W. Muir

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Title full:Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{?³-C(CF₃)C(CF ₃)C(Me)=C(Ph)SPrⁱ}(CF₃C=CCF ₃)(?⁵-C₅H₅)], [WSPr ⁱ{?⁵-C(CF₃)C(CF₃)C(CF ₃)=C(CF₃)C(Me)=C(Ph)}(?⁵-C ₅H₅)]. Addition of alkynes to isomeric ?²-C,C-vinyl [M{?³-C(CF₃)C(CF₃)SR'} (CF ₃C=CCF₃)(?⁵-C₅H ₅)] (M = Mo, W; R' = Prⁱ) and bis-alkyne complexes [MSR' (CF₃C=CCF₃)₂(? ⁵- C₅H₅)] (M = W, R' = 4-MeC ₆H₄) gives new metallacycles formed by linking of two or three alkynes; X-ray analyses reveal two modes of bonding for the tris alkyne (CR)₆ ligands.

Original language	English
Pages (from-to)	549-551
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39890000549
Publication status	Published - 1989

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Agh-Atabay, N. M., Davidson, J. L., Douglas, G., & Muir, K. W. (1989). Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{η³-C(CF₃)C(CF ₃)C(Me)=C(Ph)SPrⁱ}(CF₃C≡CCF ₃)(η⁵-C₅H₅)], [WSPr ⁱ{η⁵-C(CF₃)C(CF₃)C(CF ₃)=C(CF₃)C(Me)=C(Ph)... Journal of the Chemical Society, Chemical Communications, (9), 549-551. https://doi.org/10.1039/C39890000549

@article{f7249f2cda7345509ec62eee86d98dd6,

title = "Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{η3-C(CF3)C(CF 3)C(Me)=C(Ph)SPri}(CF3C≡CCF 3)(η5-C5H5)], [WSPr i{η5-C(CF3)C(CF3)C(CF 3)=C(CF3)C(Me)=C(Ph)...",

abstract = "Title full:Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{?3-C(CF3)C(CF 3)C(Me)=C(Ph)SPri}(CF3C=CCF 3)(?5-C5H5)], [WSPr i{?5-C(CF3)C(CF3)C(CF 3)=C(CF3)C(Me)=C(Ph)}(?5-C 5H5)]. Addition of alkynes to isomeric ?2-C,C-vinyl [M{?3-C(CF3)C(CF3)SR'} (CF 3C=CCF3)(?5-C5H 5)] (M = Mo, W; R' = Pri) and bis-alkyne complexes [MSR' (CF3C=CCF3)2(? 5- C5H5)] (M = W, R' = 4-MeC 6H4) gives new metallacycles formed by linking of two or three alkynes; X-ray analyses reveal two modes of bonding for the tris alkyne (CR)6 ligands.",

author = "Agh-Atabay, {Naz M.} and Davidson, {Jack L.} and Graeme Douglas and Muir, {Kenneth W.}",

year = "1989",

doi = "10.1039/C39890000549",

language = "English",

pages = "549--551",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "9",

}

Agh-Atabay, NM, Davidson, JL, Douglas, G & Muir, KW 1989, 'Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{η³-C(CF₃)C(CF ₃)C(Me)=C(Ph)SPrⁱ}(CF₃C≡CCF ₃)(η⁵-C₅H₅)], [WSPr ⁱ{η⁵-C(CF₃)C(CF₃)C(CF ₃)=C(CF₃)C(Me)=C(Ph)...', Journal of the Chemical Society, Chemical Communications, no. 9, pp. 549-551. https://doi.org/10.1039/C39890000549

Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{η³-C(CF₃)C(CF ₃)C(Me)=C(Ph)SPrⁱ}(CF₃C≡CCF ₃)(η⁵-C₅H₅)], [WSPr ⁱ{η⁵-C(CF₃)C(CF₃)C(CF ₃)=C(CF₃)C(Me)=C(Ph)... / Agh-Atabay, Naz M.; Davidson, Jack L.; Douglas, Graeme et al.
In: Journal of the Chemical Society, Chemical Communications, No. 9, 1989, p. 549-551.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{η3-C(CF3)C(CF 3)C(Me)=C(Ph)SPri}(CF3C≡CCF 3)(η5-C5H5)], [WSPr i{η5-C(CF3)C(CF3)C(CF 3)=C(CF3)C(Me)=C(Ph)...

AU - Agh-Atabay, Naz M.

AU - Davidson, Jack L.

AU - Douglas, Graeme

AU - Muir, Kenneth W.

PY - 1989

Y1 - 1989

N2 - Title full:Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{?3-C(CF3)C(CF 3)C(Me)=C(Ph)SPri}(CF3C=CCF 3)(?5-C5H5)], [WSPr i{?5-C(CF3)C(CF3)C(CF 3)=C(CF3)C(Me)=C(Ph)}(?5-C 5H5)]. Addition of alkynes to isomeric ?2-C,C-vinyl [M{?3-C(CF3)C(CF3)SR'} (CF 3C=CCF3)(?5-C5H 5)] (M = Mo, W; R' = Pri) and bis-alkyne complexes [MSR' (CF3C=CCF3)2(? 5- C5H5)] (M = W, R' = 4-MeC 6H4) gives new metallacycles formed by linking of two or three alkynes; X-ray analyses reveal two modes of bonding for the tris alkyne (CR)6 ligands.

AB - Title full:Metal-promoted alkyne trimerisation leading to novel metallacycles. The molecular structures of [Mo{?3-C(CF3)C(CF 3)C(Me)=C(Ph)SPri}(CF3C=CCF 3)(?5-C5H5)], [WSPr i{?5-C(CF3)C(CF3)C(CF 3)=C(CF3)C(Me)=C(Ph)}(?5-C 5H5)]. Addition of alkynes to isomeric ?2-C,C-vinyl [M{?3-C(CF3)C(CF3)SR'} (CF 3C=CCF3)(?5-C5H 5)] (M = Mo, W; R' = Pri) and bis-alkyne complexes [MSR' (CF3C=CCF3)2(? 5- C5H5)] (M = W, R' = 4-MeC 6H4) gives new metallacycles formed by linking of two or three alkynes; X-ray analyses reveal two modes of bonding for the tris alkyne (CR)6 ligands.

UR - http://www.scopus.com/inward/record.url?scp=51149216071&partnerID=8YFLogxK

U2 - 10.1039/C39890000549

DO - 10.1039/C39890000549

M3 - Article

SN - 0022-4936

SP - 549

EP - 551

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 9