Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF3)·C(CF 3)·C(O)SMe(η5-C5H 5)(CO)2] and [WC(CO2Me)C(CO2Me) ·C(O)SMe(η5-C5H5)(CO)2]

Jack L. Davidson; Mahmoud Shiralian; Ljubica Manojlovic-Muir; Kenneth W. Muir

doi:10.1039/C39790000030

Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF₃)·C(CF ₃)·C(O)SMe(η⁵-C₅H ₅)(CO)₂] and [WC(CO₂Me)C(CO₂Me) ·C(O)SMe(η⁵-C₅H₅)(CO)₂]

Jack L. Davidson
, Mahmoud Shiralian
, Ljubica Manojlovic-Muir
, Kenneth W. Muir

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The migration of an alkylthio group across an enone ligand co-ordinated to tungsten has been demonstrated; X-ray diffraction studies have established the structures of the two isomeric products, one of which contains a novel alkyl-carbene ligand which functions as a three-electron donor to the metal.

Original language	English
Pages (from-to)	30-32
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39790000030
Publication status	Published - 1979

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10.1039/C39790000030

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Davidson, J. L., Shiralian, M., Manojlovic-Muir, L., & Muir, K. W. (1979). Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF₃)·C(CF ₃)·C(O)SMe(η⁵-C₅H ₅)(CO)₂] and [WC(CO₂Me)C(CO₂Me) ·C(O)SMe(η⁵-C₅H₅)(CO)₂]. Journal of the Chemical Society, Chemical Communications, (1), 30-32. https://doi.org/10.1039/C39790000030

@article{e3ada3ffda694e87a3f0e1093c34d538,

title = "Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF3)·C(CF 3)·C(O)SMe(η5-C5H 5)(CO)2] and [WC(CO2Me)C(CO2Me) ·C(O)SMe(η5-C5H5)(CO)2]",

abstract = "The migration of an alkylthio group across an enone ligand co-ordinated to tungsten has been demonstrated; X-ray diffraction studies have established the structures of the two isomeric products, one of which contains a novel alkyl-carbene ligand which functions as a three-electron donor to the metal.",

author = "Davidson, \{Jack L.\} and Mahmoud Shiralian and Ljubica Manojlovic-Muir and Muir, \{Kenneth W.\}",

year = "1979",

doi = "10.1039/C39790000030",

language = "English",

pages = "30--32",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "1",

}

Davidson, JL, Shiralian, M, Manojlovic-Muir, L & Muir, KW 1979, 'Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF₃)·C(CF ₃)·C(O)SMe(η⁵-C₅H ₅)(CO)₂] and [WC(CO₂Me)C(CO₂Me) ·C(O)SMe(η⁵-C₅H₅)(CO)₂]', Journal of the Chemical Society, Chemical Communications, no. 1, pp. 30-32. https://doi.org/10.1039/C39790000030

Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF₃)·C(CF ₃)·C(O)SMe(η⁵-C₅H ₅)(CO)₂] and [WC(CO₂Me)C(CO₂Me) ·C(O)SMe(η⁵-C₅H₅)(CO)₂]. / Davidson, Jack L.; Shiralian, Mahmoud; Manojlovic-Muir, Ljubica et al.
In: Journal of the Chemical Society, Chemical Communications, No. 1, 1979, p. 30-32.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF3)·C(CF 3)·C(O)SMe(η5-C5H 5)(CO)2] and [WC(CO2Me)C(CO2Me) ·C(O)SMe(η5-C5H5)(CO)2]

AU - Davidson, Jack L.

AU - Shiralian, Mahmoud

AU - Manojlovic-Muir, Ljubica

AU - Muir, Kenneth W.

PY - 1979

Y1 - 1979

N2 - The migration of an alkylthio group across an enone ligand co-ordinated to tungsten has been demonstrated; X-ray diffraction studies have established the structures of the two isomeric products, one of which contains a novel alkyl-carbene ligand which functions as a three-electron donor to the metal.

AB - The migration of an alkylthio group across an enone ligand co-ordinated to tungsten has been demonstrated; X-ray diffraction studies have established the structures of the two isomeric products, one of which contains a novel alkyl-carbene ligand which functions as a three-electron donor to the metal.

UR - https://www.scopus.com/pages/publications/0011447129

U2 - 10.1039/C39790000030

DO - 10.1039/C39790000030

M3 - Article

SN - 0022-4936

SP - 30

EP - 32

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 1

ER -

Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF₃)·C(CF ₃)·C(O)SMe(η⁵-C₅H ₅)(CO)₂] and [WC(CO₂Me)C(CO₂Me) ·C(O)SMe(η⁵-C₅H₅)(CO)₂]

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