TY - JOUR
T1 - Metal-promoted 1,3-sulphur shifts leading to novel metallocycles. X-Ray crystal and molecular structures of [WC(CF3)·C(CF 3)·C(O)SMe(η5-C5H 5)(CO)2] and [WC(CO2Me)C(CO2Me) ·C(O)SMe(η5-C5H5)(CO)2]
AU - Davidson, Jack L.
AU - Shiralian, Mahmoud
AU - Manojlovic-Muir, Ljubica
AU - Muir, Kenneth W.
PY - 1979
Y1 - 1979
N2 - The migration of an alkylthio group across an enone ligand co-ordinated to tungsten has been demonstrated; X-ray diffraction studies have established the structures of the two isomeric products, one of which contains a novel alkyl-carbene ligand which functions as a three-electron donor to the metal.
AB - The migration of an alkylthio group across an enone ligand co-ordinated to tungsten has been demonstrated; X-ray diffraction studies have established the structures of the two isomeric products, one of which contains a novel alkyl-carbene ligand which functions as a three-electron donor to the metal.
UR - http://www.scopus.com/inward/record.url?scp=0011447129&partnerID=8YFLogxK
U2 - 10.1039/C39790000030
DO - 10.1039/C39790000030
M3 - Article
SN - 0022-4936
SP - 30
EP - 32
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 1
ER -