Mechanisms of alkyne trimerisation at molybdenum and tungsten centres leading to novel metallacycles: Crystal and molecular structures of two isomeric forms of [Mo{C(CF₃)C(CF₃)C(CF₃)C(CF ₃)C(CO₂Me)C(CO₂Me)-(SPr ⁱ)}(η⁵-C₅H₅)]

Chemistry

• R 100%
• Metal 26%
• Compound Isomer 15%
• Alkyne 15%
• Ligand 10%
• Metallacycle 10%
• Trimerization 10%
• Chemical Bond 10%
• Chemical Reaction 10%
• Chemical Reaction Product 10%
• Primary Structure 10%
• Ambient Reaction Temperature 10%
• Sulfur 10%
• X-Ray Diffraction 10%
• Fluorine 5%
• Alkene 5%
• Fluoride 5%
• Tungsten 5%
• Oligomerization 5%
• 19F NMR Spectroscopy 5%
• Chemical Kinetics Characteristics 5%
• Crystalline Material 5%
• Carbon 5%
• Molecular Structure 5%
• Trimer 5%
• Molybdenum 5%
• Reaction Mechanism 5%