Mechanical properties of attapulgite clay reinforced polyurethane shape-memory nanocomposites

Bin Xu, Wei Min Huang, Yu Tao Pei, Zezhi Chen, Arno Manfred Kraft, Robert Lewis Reuben, J Th M De Hosson, Yong Qing Fu

Research output: Contribution to journalArticle

88 Citations (Scopus)

Abstract

Nanocomposites based on attapulgite clay and shape-memory polyurethane were fabricated by mechanical mixing. The mechanical properties of samples were evaluated using a micro-indentation tester. The untreated commercial attapulgite clay resulted in a significant decrease in glass transition temperature and hardness of the nanocomposite due to the presence of moisture as well as the clay's amorphous structure and surface hydroxyl groups. The attapulgite nanoparticles were heat-treated at 850 °C, which resulted in crystallization of the particles and formation of layered attapulgite structure. The hardness of the nanocomposites composed of the heat treated clay powder dramatically increased as a function of clay content, which is attributed to the homogeneous dispersion of the nanofillers in the polymer matrix and strong filler-polymer interactions. Shape recovery of indentations has been demonstrated upon heating. © 2009 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)1904-1911
Number of pages8
JournalEuropean Polymer Journal
Volume45
Issue number7
DOIs
Publication statusPublished - Jul 2009

Keywords

  • Shape memory
  • Nanocomposites
  • Polyurethane
  • Nano-clay
  • Vickers indentation
  • Microhardness
  • SILICATE NANOCOMPOSITES
  • GLASS-TRANSITION
  • POLYMERS
  • COMPOSITES
  • PALYGORSKITES
  • MICROHARDNESS
  • INDENTATION
  • TEMPERATURE
  • PERFORMANCE
  • SEPIOLITES

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