Measurement of Henry's Law constant and infinite dilution activity coefficient of isopropyl mercaptan and isobutyl mercaptan in (methyldiethanolamine (1) + water (2)) with w1 = 0.25 and 0.50 at temperature of (298 to 348) K using inert gas stripping method

Rohani Mohd Zin, Christophe Coquelet, Alain Valtz, Mohamed I. Abdul Mutalib, Khalik Mohamad Sabil

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In this study, the Henry's Law constant and the activity coefficients in infinite dilution in a mass fraction of (25 and 50)% of methyldiethanolamine (MDEA) aqueous solution within the temperature range of (298 to 348) K at atmospheric pressure, were measured. An inert gas stripping method was used to perform all the measurements. The new values of Henry's Law constant and the activity coefficients in infinite dilution correlation with solute molecular size were explained. The influence of the solvent is discussed taking into consideration the heat of absorptions for different MDEA concentrations. Experimental results are compared to literature data wherever available.

Original languageEnglish
Pages (from-to)193-199
Number of pages7
JournalJournal of Chemical Thermodynamics
Volume93
Early online date13 Oct 2015
DOIs
Publication statusPublished - Feb 2016

Keywords

  • Heat of solution
  • Limiting activity coefficient
  • Solubility

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)

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