Mössbauer spectroscopic studies of chromium depletion in a 310 stainless steel during air oxidation

I. Stewart, Michael J Tricker, J. A. Cairns

    Research output: Contribution to journalArticle

    Abstract

    The application of conversion electron Mössbauer spectroscopy (CEMS) to the oxidation of an ultra-thin 310 stainless steel foil is presented. It is shown that during oxidation the foil deviates from the expected oxidation behaviour, derived from thick film kinetics, due to the effects of chromium depletion. Evidence is presented for the observation, in the spectra, of chromium depletion. The experimentally derived time-to-failure is compared with that predicted by theory. © 1986.

    Original languageEnglish
    Pages (from-to)1041-1055
    Number of pages15
    JournalCorrosion Science
    Volume26
    Issue number12
    Publication statusPublished - 1986

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    stainless steels
    chromium
    depletion
    oxidation
    foils
    air
    thick films
    electron spectroscopy
    kinetics

    Cite this

    Stewart, I. ; Tricker, Michael J ; Cairns, J. A. / Mössbauer spectroscopic studies of chromium depletion in a 310 stainless steel during air oxidation. In: Corrosion Science. 1986 ; Vol. 26, No. 12. pp. 1041-1055.
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    abstract = "The application of conversion electron M{\"o}ssbauer spectroscopy (CEMS) to the oxidation of an ultra-thin 310 stainless steel foil is presented. It is shown that during oxidation the foil deviates from the expected oxidation behaviour, derived from thick film kinetics, due to the effects of chromium depletion. Evidence is presented for the observation, in the spectra, of chromium depletion. The experimentally derived time-to-failure is compared with that predicted by theory. {\circledC} 1986.",
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    Stewart, I, Tricker, MJ & Cairns, JA 1986, 'Mössbauer spectroscopic studies of chromium depletion in a 310 stainless steel during air oxidation', Corrosion Science, vol. 26, no. 12, pp. 1041-1055.

    Mössbauer spectroscopic studies of chromium depletion in a 310 stainless steel during air oxidation. / Stewart, I.; Tricker, Michael J; Cairns, J. A.

    In: Corrosion Science, Vol. 26, No. 12, 1986, p. 1041-1055.

    Research output: Contribution to journalArticle

    TY - JOUR

    T1 - Mössbauer spectroscopic studies of chromium depletion in a 310 stainless steel during air oxidation

    AU - Stewart, I.

    AU - Tricker, Michael J

    AU - Cairns, J. A.

    PY - 1986

    Y1 - 1986

    N2 - The application of conversion electron Mössbauer spectroscopy (CEMS) to the oxidation of an ultra-thin 310 stainless steel foil is presented. It is shown that during oxidation the foil deviates from the expected oxidation behaviour, derived from thick film kinetics, due to the effects of chromium depletion. Evidence is presented for the observation, in the spectra, of chromium depletion. The experimentally derived time-to-failure is compared with that predicted by theory. © 1986.

    AB - The application of conversion electron Mössbauer spectroscopy (CEMS) to the oxidation of an ultra-thin 310 stainless steel foil is presented. It is shown that during oxidation the foil deviates from the expected oxidation behaviour, derived from thick film kinetics, due to the effects of chromium depletion. Evidence is presented for the observation, in the spectra, of chromium depletion. The experimentally derived time-to-failure is compared with that predicted by theory. © 1986.

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    SP - 1041

    EP - 1055

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    JF - Corrosion Science

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