LUMINESCENCE STUDIES OF MOLECULAR MOBILITY IN THE POLYMERIC SOLID STATE.

Ian Soutar, John Toynbee

Research output: Contribution to journalArticle

Abstract

Application of luminescent probes, dispersed in the polymer matrix, permits study of the extent to which macromolecular motions affect the microviscosity of the environment of low molar mass solutes. Anisotropy measurements involving labelled polymers allow direct and quantitative examination of macromolecular relaxations and, through judicious choice of label, can elucidate the molecular mechanisms responsible for transitions evident in dynamic mechanic and dielectric relaxation spectra. Both types of experiment have been employed in this study which is concerned with the relaxation behavior of poly(n-butyl acrylate).

Original languageEnglish
Pages (from-to)338-339
Number of pages2
JournalPolymer Preprints
Volume27
Issue number2
Publication statusPublished - Sep 1986
EventProceedings of the 21st International Quantum Electronics Conference (IQEC'94) - Anaheim, CA, USA
Duration: 8 May 199413 May 1994

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Molar mass
Dielectric relaxation
Polymer matrix
Luminescence
Labels
Mechanics
Polymers
Anisotropy
Experiments
poly(n-butyl acrylate)

Cite this

Soutar, Ian ; Toynbee, John. / LUMINESCENCE STUDIES OF MOLECULAR MOBILITY IN THE POLYMERIC SOLID STATE. In: Polymer Preprints. 1986 ; Vol. 27, No. 2. pp. 338-339.
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Soutar, I & Toynbee, J 1986, 'LUMINESCENCE STUDIES OF MOLECULAR MOBILITY IN THE POLYMERIC SOLID STATE.', Polymer Preprints, vol. 27, no. 2, pp. 338-339.

LUMINESCENCE STUDIES OF MOLECULAR MOBILITY IN THE POLYMERIC SOLID STATE. / Soutar, Ian; Toynbee, John.

In: Polymer Preprints, Vol. 27, No. 2, 09.1986, p. 338-339.

Research output: Contribution to journalArticle

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