Liqud-gas phase behavior of Stockmayer fluid with high dipolar moment

  • Yurij V. Kalyuzhnyi*
  • , I. A. Protsykevytch
  • , P. T. Cummings
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A multi-density version of the thermodynamic perturbation theory for associative fluids with central force associative potential is developed. The theory is used to describe the liquid-gas phase behavior of Stochmayer fluid with different values of the dipole moment ranging from low to high. Results of the theory are in a reasonable agreement with corresponding computer simulation results in a whole range of the dipole moment values studied. Contrary to previous computer simulation findings our calculations predict the occurrence of the liquid-gas phase coexistence for the soft-sphere dipole fluid model.

Original languageEnglish
Pages (from-to)553-562
Number of pages10
JournalCondensed Matter Physics
Volume10
Issue number4
DOIs
Publication statusPublished - 2007

Keywords

  • Association
  • Dipole moment
  • Phase diagram
  • Stockmayer fluid

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physics and Astronomy (miscellaneous)

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