Abstract
A multi-density version of the thermodynamic perturbation theory for associative fluids with central force associative potential is developed. The theory is used to describe the liquid-gas phase behavior of Stochmayer fluid with different values of the dipole moment ranging from low to high. Results of the theory are in a reasonable agreement with corresponding computer simulation results in a whole range of the dipole moment values studied. Contrary to previous computer simulation findings our calculations predict the occurrence of the liquid-gas phase coexistence for the soft-sphere dipole fluid model.
| Original language | English |
|---|---|
| Pages (from-to) | 553-562 |
| Number of pages | 10 |
| Journal | Condensed Matter Physics |
| Volume | 10 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2007 |
Keywords
- Association
- Dipole moment
- Phase diagram
- Stockmayer fluid
ASJC Scopus subject areas
- Condensed Matter Physics
- Physics and Astronomy (miscellaneous)
Fingerprint
Dive into the research topics of 'Liqud-gas phase behavior of Stockmayer fluid with high dipolar moment'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver