Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

David Kitcatt; Eva Pogacar; Le Mi; Simon Nicolle; Ai-Lan Lee

doi:10.1021/acs.joc.4c02163

Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

David Kitcatt, Eva Pogacar, Le Mi, Simon Nicolle, Ai-Lan Lee

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Abstract

Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

Original language	English
Pages (from-to)	16055-16059
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	89
Issue number	21
Early online date	22 Oct 2024
DOIs	https://doi.org/10.1021/acs.joc.4c02163
Publication status	Published - 1 Nov 2024

Keywords

Absorption
Chemical Reactions
Electromagnetic Radiation
Light
Mixtures

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abstract = "Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.",

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author = "David Kitcatt and Eva Pogacar and Le Mi and Simon Nicolle and Ai-Lan Lee",

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AU - Kitcatt, David

AU - Pogacar, Eva

AU - Mi, Le

AU - Nicolle, Simon

AU - Lee, Ai-Lan

PY - 2024/11/1

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N2 - Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

AB - Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

KW - Absorption

KW - Chemical Reactions

KW - Electromagnetic Radiation

KW - Light

KW - Mixtures

UR - https://www.scopus.com/pages/publications/85207272883

U2 - 10.1021/acs.joc.4c02163

DO - 10.1021/acs.joc.4c02163

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ER -

Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

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Keywords

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