Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

David Kitcatt; Eva Pogacar; Le Mi; Simon Nicolle; Ai-Lan Lee

doi:10.1021/acs.joc.4c02163

Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

David Kitcatt, Eva Pogacar, Le Mi, Simon Nicolle, Ai-Lan Lee

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

12 Downloads (Pure)

Abstract

Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

Original language	English
Pages (from-to)	16055-16059
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	89
Issue number	21
Early online date	22 Oct 2024
DOIs	https://doi.org/10.1021/acs.joc.4c02163
Publication status	Published - 1 Nov 2024

Keywords

Absorption
Chemical Reactions
Electromagnetic Radiation
Light
Mixtures

Access to Document

10.1021/acs.joc.4c02163Licence: CC BY

Download pdfFinal published version, 1.81 MBLicence: CC BY

Cite this

@article{288b10a638a5491080f9a23e0ca2e844,

title = "Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst",

abstract = "Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.",

keywords = "Absorption, Chemical Reactions, Electromagnetic Radiation, Light, Mixtures",

author = "David Kitcatt and Eva Pogacar and Le Mi and Simon Nicolle and Ai-Lan Lee",

note = "Publisher Copyright: {\textcopyright} 2024 The Authors. Published by American Chemical Society.",

year = "2024",

month = nov,

day = "1",

doi = "10.1021/acs.joc.4c02163",

language = "English",

volume = "89",

pages = "16055--16059",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

AU - Kitcatt, David

AU - Pogacar, Eva

AU - Mi, Le

AU - Nicolle, Simon

AU - Lee, Ai-Lan

PY - 2024/11/1

Y1 - 2024/11/1

N2 - Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

AB - Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

KW - Absorption

KW - Chemical Reactions

KW - Electromagnetic Radiation

KW - Light

KW - Mixtures

UR - http://www.scopus.com/inward/record.url?scp=85207272883&partnerID=8YFLogxK

U2 - 10.1021/acs.joc.4c02163

DO - 10.1021/acs.joc.4c02163

M3 - Article

C2 - 39438444

SN - 0022-3263

VL - 89

SP - 16055

EP - 16059

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this