Layering Behavior and Axial Phase Equilibria of Pure Water and Water + Carbon Dioxide Inside Single Wall Carbon Nanotubes

José L. Rivera; Clare McCabe; Peter T. Cummings

doi:10.1021/nl0257566

Layering Behavior and Axial Phase Equilibria of Pure Water and Water + Carbon Dioxide Inside Single Wall Carbon Nanotubes

José L. Rivera, Clare McCabe, Peter T. Cummings^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

We have studied the phase equilibrium and layering behavior of the liquid phase in water and water + CO₂ systems inside single wall carbon nanotubes. The system containing pure water was examined at temperatures between 274 and 500 K. At low temperatures and close to the wall of the nanotube, the formation of layers enclosing the liquid phase was observed. Upon addition of CO₂, gas-liquid equilibrium was observed, resulting in an enhanced layering effect in the liquid phase.

Original language	English
Pages (from-to)	1427-1431
Number of pages	5
Journal	Nano Letters
Volume	2
Issue number	12
DOIs	https://doi.org/10.1021/nl0257566
Publication status	Published - 1 Dec 2002

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering

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abstract = "We have studied the phase equilibrium and layering behavior of the liquid phase in water and water + CO2 systems inside single wall carbon nanotubes. The system containing pure water was examined at temperatures between 274 and 500 K. At low temperatures and close to the wall of the nanotube, the formation of layers enclosing the liquid phase was observed. Upon addition of CO2, gas-liquid equilibrium was observed, resulting in an enhanced layering effect in the liquid phase.",

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AU - Cummings, Peter T.

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AB - We have studied the phase equilibrium and layering behavior of the liquid phase in water and water + CO2 systems inside single wall carbon nanotubes. The system containing pure water was examined at temperatures between 274 and 500 K. At low temperatures and close to the wall of the nanotube, the formation of layers enclosing the liquid phase was observed. Upon addition of CO2, gas-liquid equilibrium was observed, resulting in an enhanced layering effect in the liquid phase.

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Layering Behavior and Axial Phase Equilibria of Pure Water and Water + Carbon Dioxide Inside Single Wall Carbon Nanotubes

Abstract

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