Laser photofragment spectroscopy of jet-cooled CClF2NO

M. R S McCoustra; J. A. Dyet; J. Pfab

Laser photofragment spectroscopy of jet-cooled CClF₂NO

M. R S McCoustra, J. A. Dyet, J. Pfab

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Photofragment yield spectra of jet-cooled CClF₂NO in the visible region have been recorded using pulsed laser dissociation in conjunction with two-photon LIF probing of the nascent NO fragment. Photodissociation of the cold parent at 646.6 nm yields NO with a statistical rotational state distribution but a colder than statistical spin-orbit distribution. A dissociation energy of 13500 ± 350 cm^-1 has been evaluated for the C-N bond of the parent nitroso compound. © 1987.

Original language	English
Pages (from-to)	231-235
Number of pages	5
Journal	Chemical Physics Letters
Volume	136
Issue number	3-4
Publication status	Published - 8 May 1987

Cite this

@article{28a90f914f13496c9c19fd9bd385f02c,

title = "Laser photofragment spectroscopy of jet-cooled CClF2NO",

abstract = "Photofragment yield spectra of jet-cooled CClF2NO in the visible region have been recorded using pulsed laser dissociation in conjunction with two-photon LIF probing of the nascent NO fragment. Photodissociation of the cold parent at 646.6 nm yields NO with a statistical rotational state distribution but a colder than statistical spin-orbit distribution. A dissociation energy of 13500 ± 350 cm-1 has been evaluated for the C-N bond of the parent nitroso compound. {\textcopyright} 1987.",

author = "McCoustra, \{M. R S\} and Dyet, \{J. A.\} and J. Pfab",

year = "1987",

month = may,

day = "8",

language = "English",

volume = "136",

pages = "231--235",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "3-4",

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TY - JOUR

T1 - Laser photofragment spectroscopy of jet-cooled CClF2NO

AU - McCoustra, M. R S

AU - Dyet, J. A.

AU - Pfab, J.

PY - 1987/5/8

Y1 - 1987/5/8

N2 - Photofragment yield spectra of jet-cooled CClF2NO in the visible region have been recorded using pulsed laser dissociation in conjunction with two-photon LIF probing of the nascent NO fragment. Photodissociation of the cold parent at 646.6 nm yields NO with a statistical rotational state distribution but a colder than statistical spin-orbit distribution. A dissociation energy of 13500 ± 350 cm-1 has been evaluated for the C-N bond of the parent nitroso compound. © 1987.

AB - Photofragment yield spectra of jet-cooled CClF2NO in the visible region have been recorded using pulsed laser dissociation in conjunction with two-photon LIF probing of the nascent NO fragment. Photodissociation of the cold parent at 646.6 nm yields NO with a statistical rotational state distribution but a colder than statistical spin-orbit distribution. A dissociation energy of 13500 ± 350 cm-1 has been evaluated for the C-N bond of the parent nitroso compound. © 1987.

M3 - Article

SN - 0009-2614

VL - 136

SP - 231

EP - 235

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

Laser photofragment spectroscopy of jet-cooled CClF2NO

Abstract

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Laser photofragment spectroscopy of jet-cooled CClF₂NO