Laser photofragment spectroscopy of jet-cooled CClF2NO

M. R S McCoustra, J. A. Dyet, J. Pfab

Research output: Contribution to journalArticle

Abstract

Photofragment yield spectra of jet-cooled CClF2NO in the visible region have been recorded using pulsed laser dissociation in conjunction with two-photon LIF probing of the nascent NO fragment. Photodissociation of the cold parent at 646.6 nm yields NO with a statistical rotational state distribution but a colder than statistical spin-orbit distribution. A dissociation energy of 13500 ± 350 cm-1 has been evaluated for the C-N bond of the parent nitroso compound. © 1987.

Original languageEnglish
Pages (from-to)231-235
Number of pages5
JournalChemical Physics Letters
Volume136
Issue number3-4
Publication statusPublished - 8 May 1987

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