Abstract
Photofragment yield spectra of jet-cooled CClF2NO in the visible region have been recorded using pulsed laser dissociation in conjunction with two-photon LIF probing of the nascent NO fragment. Photodissociation of the cold parent at 646.6 nm yields NO with a statistical rotational state distribution but a colder than statistical spin-orbit distribution. A dissociation energy of 13500 ± 350 cm-1 has been evaluated for the C-N bond of the parent nitroso compound. © 1987.
Original language | English |
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Pages (from-to) | 231-235 |
Number of pages | 5 |
Journal | Chemical Physics Letters |
Volume | 136 |
Issue number | 3-4 |
Publication status | Published - 8 May 1987 |