Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Scott J Dalgarno; Michaele J Hardie; John E Warren; Colin L Raston

doi:10.1039/b407207c

Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Scott J Dalgarno, Michaele J Hardie, John E Warren, Colin L Raston

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

Original language	English
Pages (from-to)	2413-2416
Number of pages	4
Journal	Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/b407207c
Publication status	Published - 2004

Access to Document

10.1039/b407207c

Cite this

@article{1032beeb7107458ba323b1d139114a3e,

title = "Lanthanide crown ether complexes of p-sulfonatocalix[5]arene",

abstract = "Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.",

author = "Dalgarno, \{Scott J\} and Hardie, \{Michaele J\} and Warren, \{John E\} and Raston, \{Colin L\}",

year = "2004",

doi = "10.1039/b407207c",

language = "English",

pages = "2413--2416",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

AU - Dalgarno, Scott J

AU - Hardie, Michaele J

AU - Warren, John E

AU - Raston, Colin L

PY - 2004

Y1 - 2004

N2 - Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

AB - Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

U2 - 10.1039/b407207c

DO - 10.1039/b407207c

M3 - Article

SN - 1477-9226

SP - 2413

EP - 2416

JO - Dalton Transactions

JF - Dalton Transactions

IS - 16

ER -

Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Abstract

Access to Document

Fingerprint

Cite this