Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Scott J Dalgarno; Michaele J Hardie; John E Warren; Colin L Raston

doi:10.1039/b407207c

Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Scott J Dalgarno, Michaele J Hardie, John E Warren, Colin L Raston

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38 Citations (Scopus)

Abstract

Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

Original language	English
Pages (from-to)	2413-2416
Number of pages	4
Journal	Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/b407207c
Publication status	Published - 2004

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title = "Lanthanide crown ether complexes of p-sulfonatocalix[5]arene",

abstract = "Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.",

author = "Dalgarno, {Scott J} and Hardie, {Michaele J} and Warren, {John E} and Raston, {Colin L}",

year = "2004",

doi = "10.1039/b407207c",

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journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

number = "16",

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T1 - Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

AU - Dalgarno, Scott J

AU - Hardie, Michaele J

AU - Warren, John E

AU - Raston, Colin L

PY - 2004

Y1 - 2004

N2 - Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

AB - Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.

U2 - 10.1039/b407207c

DO - 10.1039/b407207c

M3 - Article

SN - 1477-9226

SP - 2413

EP - 2416

JO - Dalton Transactions

JF - Dalton Transactions

IS - 16

ER -

Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Abstract

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