Lanthanide crown ether complexes of p-sulfonatocalix[5]arene

Scott J Dalgarno, Michaele J Hardie, John E Warren, Colin L Raston

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Two types of arrays are formed in water involving aza-crown ethers, p-sulfonatocalix[5] arene and europium(III) ions. One is a co-ordination polymer connecting calixarenes, sodium ions and lanthanide ions based on `ferris wheel' moieties incorporating aza-18-crown-6 and sodium ions. The second structure is a host-guest arrangement with di-protonated diaza-18-crown-6 in the cavity of the calixarenes as part of secondary coordination spheres of aquated europium(III) ions.
Original languageEnglish
Pages (from-to)2413-2416
Number of pages4
JournalDalton Transactions
Issue number16
DOIs
Publication statusPublished - 2004

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