Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

Thomas D. Roberts; Marc A. Little; Floriana Tuna; Colin A. Kilner; Malcolm A. Halcrow

doi:10.1039/c3cc43613f

Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

Thomas D. Roberts, Marc A. Little, Floriana Tuna, Colin A. Kilner, Malcolm A. Halcrow^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Two salts of [FeL₂]²⁺ (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes.

Original language	English
Pages (from-to)	6280-6282
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	56
DOIs	https://doi.org/10.1039/c3cc43613f
Publication status	Published - 18 Jul 2013

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc43613f

Cite this

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title = "Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes",

abstract = "Two salts of [FeL2]2+ (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes.",

author = "Roberts, {Thomas D.} and Little, {Marc A.} and Floriana Tuna and Kilner, {Colin A.} and Halcrow, {Malcolm A.}",

year = "2013",

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doi = "10.1039/c3cc43613f",

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pages = "6280--6282",

journal = "Chemical Communications",

issn = "1359-7345",

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T1 - Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

AU - Roberts, Thomas D.

AU - Little, Marc A.

AU - Tuna, Floriana

AU - Kilner, Colin A.

AU - Halcrow, Malcolm A.

PY - 2013/7/18

Y1 - 2013/7/18

N2 - Two salts of [FeL2]2+ (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes.

AB - Two salts of [FeL2]2+ (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes.

UR - http://www.scopus.com/inward/record.url?scp=84880886176&partnerID=8YFLogxK

U2 - 10.1039/c3cc43613f

DO - 10.1039/c3cc43613f

M3 - Article

C2 - 23735978

AN - SCOPUS:84880886176

SN - 1359-7345

VL - 49

SP - 6280

EP - 6282

JO - Chemical Communications

JF - Chemical Communications

IS - 56

ER -

Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

Abstract

ASJC Scopus subject areas

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